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W4313897917 abstract "Abstract Traditional polyolefin separators cannot guarantee safety for lithium‐ion batteries at high temperature due to their low melting point, especially for high power discharge. Therefore, it is imperative to develop separators with excellent thermal stability. In this paper, we have prepared TiO 2 modified PVDF composite separators by electrospinning. When compared with commercial PE separators, this kind of composite separators show superior thermal stability at 160°C. In addition, it is found that the 0.5‐TiO 2 @PVDF separator exhibits excellent flame retardant and optimal tension strength. Meanwhile, the 0.5‐TiO 2 @PVDF separator exhibits ideal liquid electrolyte storage capacity, which improves the ionic conductivity (0.68 mS cm −1 ). As a result, the LiCoO 2 ||Li cells with 0.5‐TiO 2 @PVDF separator have high discharge capacity retention rate at a current density of 1 C (300 cycles) and excellent rate performance (1.75 mAh at 5 C). In short, nano‐TiO 2 modified PVDF separator has a great application prospect in high‐performance and high‐safety lithium‐ion batteries." @default.
W4313897917 created "2023-01-10" @default.
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W4313897917 date "2023-01-09" @default.
W4313897917 modified "2023-10-01" @default.
W4313897917 title "High‐performance <scp>nano‐TiO<sub>2</sub></scp>@polyvinylidene fluoride composite separators prepared by electrospinning for safe lithium‐ion battery" @default.
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W4313897917 doi "https://doi.org/10.1002/app.53618" @default.
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