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• W4313909995 abstract "We report herein an asymmetric cooperative process for the enantioselective 1,6-addition of β-ketoesters to in situ generated para-quinone methides with chiral Pd-aqua complexes as mixed Brønsted acid-base catalysts. Excellent yields, outstanding enantiocontrol, and good diastereoselectivity across a broad substrate range are highlights of this transformation. The utility of this reaction is further demonstrated by a facile scale up and subsequent complexity-increasing modifications." @default.
• W4313909995 created "2023-01-10" @default.
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• W4313909995 date "2023-01-10" @default.
• W4313909995 modified "2023-10-12" @default.
• W4313909995 title "Enantioselective 1,6-Addition of β-Ketoester Enolates to <i>In Situ</i> Generated <i>para</i>-Quinone Methides Enabled by Cooperative Palladium and Brønsted Acid Catalysis" @default.
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• W4313909995 doi "https://doi.org/10.1021/acs.orglett.2c04127" @default.
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