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- W4315702795 abstract "Amorphous carbon monoliths with tunable microstructures are candidate anodes for future lithium-based energy storage. Enhancing lithium storage capability and solid-state diffusion kinetics are the precondition for practical applications. Transforming intrinsic oxygen-rich defects into active sites and engineering enlarged interlayer spacing are of great importance. Herein, a novel explosion strategy is designed based on oxalate pyrolysis producing CO and CO2 to successfully prepare lignin-derived carbon monolith (LSCM) with active carbonyl (C═O) groups and enlarged interlayer spacing. Explosion promotes the demethylation of methoxyl groups and cleavage of carboxyl groups to form C═O groups. CO2 etches carbon atoms in a short time to improve the heteroatom level, expanding the interlayer spacing. ZnC2O4 is decomposed at 400 °C, simultaneously producing CO and CO2, which constructs less C═O groups and large interlayer spacing. MgC2O4 is decomposed at 450 and 480 °C, staged-weakly producing CO and CO2, which constructs more C═O groups and larger interlayer spacing. CaC2O4 is decomposed at 480 and 700 °C, staged-uniformly producing CO and CO2, which constructs abundant C═O groups and largest interlayer spacing. The LSCM prepared by staged-uniform explosion exhibits high lithium storage capacity, superior rate capability, and cycling performance. The assembled lithium ion capacitor device achieves excellent energy/power densities of 78 Wh kg-1/100 W kg-1 and superior durability (capacitance retention of 8 4.6% after 20,000 cycles). This work gives a novel insight to engineer advanced oxygen-functionalized carbons for enhanced lithium storage." @default.
- W4315702795 created "2023-01-12" @default.
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- W4315702795 date "2023-01-12" @default.
- W4315702795 modified "2023-10-18" @default.
- W4315702795 title "Explosion Strategy Engineering Oxygen-Functionalized Groups and Enlarged Interlayer Spacing of the Carbon Anode for Enhanced Lithium Storage" @default.
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- W4315702795 doi "https://doi.org/10.1021/acsami.2c21638" @default.
- W4315702795 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36633362" @default.
- W4315702795 hasPublicationYear "2023" @default.
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