Matches in SemOpenAlex for { <https://semopenalex.org/work/W4315702914> ?p ?o ?g. }
- W4315702914 endingPage "4010" @default.
- W4315702914 startingPage "4001" @default.
- W4315702914 abstract "Bipolar membranes (BPMs) are critical components of a variety of electrochemical energy technologies. Many electrochemical applications require the use of buffers to maintain stable, nonextreme pH environments, yet the impact of buffers or weak acids/bases on the electrochemical behavior of BPMs remains poorly understood. Our data for a cell containing weak electrolytes is consistent with internal pH gradients within the anion exchange membrane (AEM) or cation exchange membrane (CEM) component of the BPM that form via ionic short-circuiting processes at open-circuit. Short-circuiting results from the coupling of co-ion crossover and parasitic neutralization and leads to buffering of the bipolar interface. This phenomenon, which we term neutralization short-circuiting, serves to erode BPM efficiency by attenuating the open-circuit membrane voltage and introducing parasitic reverse bias currents associated with weak acid/base dissociation at the interface. These findings establish a mechanistic basis for the operation of BPM cells in the presence of weak acid/base electrolytes." @default.
- W4315702914 created "2023-01-12" @default.
- W4315702914 creator A5021899292 @default.
- W4315702914 creator A5045431514 @default.
- W4315702914 creator A5060568212 @default.
- W4315702914 creator A5087204138 @default.
- W4315702914 date "2023-01-12" @default.
- W4315702914 modified "2023-10-06" @default.
- W4315702914 title "Neutralization Short-Circuiting with Weak Electrolytes Erodes the Efficiency of Bipolar Membranes" @default.
- W4315702914 cites W1979937753 @default.
- W4315702914 cites W1995570577 @default.
- W4315702914 cites W2005819299 @default.
- W4315702914 cites W2022840727 @default.
- W4315702914 cites W2037733086 @default.
- W4315702914 cites W2039682269 @default.
- W4315702914 cites W2057378456 @default.
- W4315702914 cites W2058104173 @default.
- W4315702914 cites W2081305290 @default.
- W4315702914 cites W2100100522 @default.
- W4315702914 cites W2122352279 @default.
- W4315702914 cites W2139741290 @default.
- W4315702914 cites W2165219802 @default.
- W4315702914 cites W2204406952 @default.
- W4315702914 cites W2342515476 @default.
- W4315702914 cites W2551950808 @default.
- W4315702914 cites W2553791386 @default.
- W4315702914 cites W2554053139 @default.
- W4315702914 cites W2562390458 @default.
- W4315702914 cites W2779986708 @default.
- W4315702914 cites W2793421145 @default.
- W4315702914 cites W2807871659 @default.
- W4315702914 cites W2906783778 @default.
- W4315702914 cites W2943791906 @default.
- W4315702914 cites W2955787716 @default.
- W4315702914 cites W2958874224 @default.
- W4315702914 cites W2968672313 @default.
- W4315702914 cites W2972247864 @default.
- W4315702914 cites W3009640135 @default.
- W4315702914 cites W3020127799 @default.
- W4315702914 cites W3030005166 @default.
- W4315702914 cites W3040399454 @default.
- W4315702914 cites W3042815916 @default.
- W4315702914 cites W3046632533 @default.
- W4315702914 cites W3048748123 @default.
- W4315702914 cites W3084364196 @default.
- W4315702914 cites W3098466946 @default.
- W4315702914 cites W3103281222 @default.
- W4315702914 cites W3108362633 @default.
- W4315702914 cites W3108682482 @default.
- W4315702914 cites W3110994556 @default.
- W4315702914 cites W3112173652 @default.
- W4315702914 cites W3115245734 @default.
- W4315702914 cites W3115515017 @default.
- W4315702914 cites W3130333772 @default.
- W4315702914 cites W3137194994 @default.
- W4315702914 cites W3168627694 @default.
- W4315702914 cites W3170645035 @default.
- W4315702914 cites W3175576616 @default.
- W4315702914 cites W3186296770 @default.
- W4315702914 cites W3192317799 @default.
- W4315702914 cites W3199065770 @default.
- W4315702914 cites W3211162968 @default.
- W4315702914 cites W3213781658 @default.
- W4315702914 cites W4210793479 @default.
- W4315702914 cites W4225254787 @default.
- W4315702914 cites W4256163126 @default.
- W4315702914 cites W4280622195 @default.
- W4315702914 cites W4281477020 @default.
- W4315702914 cites W4283388179 @default.
- W4315702914 cites W4306804741 @default.
- W4315702914 doi "https://doi.org/10.1021/acsami.2c18685" @default.
- W4315702914 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36633314" @default.
- W4315702914 hasPublicationYear "2023" @default.
- W4315702914 type Work @default.
- W4315702914 citedByCount "1" @default.
- W4315702914 countsByYear W43157029142023 @default.
- W4315702914 crossrefType "journal-article" @default.
- W4315702914 hasAuthorship W4315702914A5021899292 @default.
- W4315702914 hasAuthorship W4315702914A5045431514 @default.
- W4315702914 hasAuthorship W4315702914A5060568212 @default.
- W4315702914 hasAuthorship W4315702914A5087204138 @default.
- W4315702914 hasBestOaLocation W43157029141 @default.
- W4315702914 hasConcept C102931765 @default.
- W4315702914 hasConcept C119599485 @default.
- W4315702914 hasConcept C127413603 @default.
- W4315702914 hasConcept C14086860 @default.
- W4315702914 hasConcept C145148216 @default.
- W4315702914 hasConcept C147789679 @default.
- W4315702914 hasConcept C159654299 @default.
- W4315702914 hasConcept C165801399 @default.
- W4315702914 hasConcept C17525397 @default.
- W4315702914 hasConcept C178790620 @default.
- W4315702914 hasConcept C185592680 @default.
- W4315702914 hasConcept C192562407 @default.
- W4315702914 hasConcept C203014093 @default.
- W4315702914 hasConcept C2182769 @default.
- W4315702914 hasConcept C41625074 @default.
- W4315702914 hasConcept C42360764 @default.