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- W4315703040 abstract "Selective oxidation of methane to methanol by molecular oxygen is a fascinating route for upgrading abundant methane resource and represents one of the most challenging reactions in chemistry due to the overwhelmingly higher reactivity of the product versus the reactant. Here, we report that monometallic gold nanoparticles loaded on mordenite zeolite efficiently catalyze the selective oxidation of methane to methanol by molecular oxygen in the presence of carbon monoxide in aqueous medium. The methanol productivity reaches 1300 μmol gcat−1 h−1 or 280 mmol gAu-1 h-1 with 75% selectivity at 150 °C, outperforming most of those reported under comparable conditions. Both hydroxyl radicals and hydroperoxide species participate in the activation and conversion of methane; the lower affinity of methanol on gold mainly accounts for higher methanol selectivity." @default.
- W4315703040 created "2023-01-12" @default.
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- W4315703040 date "2023-01-12" @default.
- W4315703040 modified "2023-10-18" @default.
- W4315703040 title "Selective oxidation of methane to methanol over Au/H-MOR" @default.
- W4315703040 doi "https://doi.org/10.26434/chemrxiv-2023-q4bfm" @default.
- W4315703040 hasPublicationYear "2023" @default.
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