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• W4315703340 endingPage "1276" @default.
• W4315703340 startingPage "1264" @default.
• W4315703340 abstract "The light alkyl carbonates are indispensable co-solvents of electrolytes for lithium-ion batteries. In this work, the tunable transesterification of dimethyl carbonate (DMC) with ethanol to co-produce ethyl methyl carbonate (EMC) and diethyl carbonate (DEC) was investigated based on an efficient catalytic system with the solid alkaline catalyst. It was found that the γ-Al2O3-supported K2CO3 catalyst exhibited high activity for the transesterification reaction, with a tunable feature for the selectivities of EMC and DEC by changing the space velocity and feed ratio of DMC to ethanol at the temperature between 120 and 150 °C. According to the results of characterizations and activity tests, a synergistic mechanism was proposed. The reaction kinetic model was also established, which displayed good agreement with the experimental results." @default.
• W4315703340 created "2023-01-12" @default.
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• W4315703340 date "2023-01-12" @default.
• W4315703340 modified "2023-10-05" @default.
• W4315703340 title "Tunable Transesterification of Dimethyl Carbonate with Ethanol on K₂CO₃/Al₂O₃ Catalysts: Kinetic Modeling" @default.
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• W4315703340 doi "https://doi.org/10.1021/acs.iecr.2c03505" @default.
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