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- W4315707213 abstract "Imidogen (NH) is the simplest nitrogen hydride that plays an important role in combustion and interstellar chemistry, and its combination with H2O is the prototypical amidation reaction of O-H bonds involving a nitrene intermediate. Herein, we report the observation of the elusive water complex of NH, a prereaction complex associated with the amidation reaction in a solid N2 matrix at 10 K. The hydrogen-bonded structure of NH···OH2 (versus HN···HOH) is confirmed via IR spectroscopy with comprehensive isotope labeling (D, 18O, and 15N) and quantum chemical calculations at the UCCSD(T)/aug-cc-pVQZ level of theory. In line with the observed absorption at 350 nm, irradiation of the complex at 365 nm leads to O-H bond insertion, yielding hydroxylamine NH2OH." @default.
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- W4315707213 date "2023-01-12" @default.
- W4315707213 modified "2023-10-18" @default.
- W4315707213 title "Water Complex of Imidogen" @default.
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- W4315707213 doi "https://doi.org/10.1021/jacs.2c12808" @default.
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