Matches in SemOpenAlex for { <https://semopenalex.org/work/W4315750237> ?p ?o ?g. }
- W4315750237 abstract "Abstract Facile access to dimeric heavier aluminum chalcogenides [(NHC)Al(Tipp)‐μ‐Ch] 2 (NHC=I i Pr (1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene, IMe 4 (1,3,4,5‐tetramethylimidazol‐2‐ylidene); Tipp=2,4,6‐ i Pr 3 C 6 H 2 ; Ch=Se, Te) by treatment of NHC‐stabilized aluminum dihydrides with elemental Se and Te is reported. The higher affinity of IMe 4 in comparison with I i Pr toward the Al center in [(NHC)Al(Tipp)‐μ‐Ch] 2 can be used for ligand exchange. Additionally, the presence of excess IMe 4 allows for cleavage of the dimers to form a rare example of a neutral multiply bonded heavier aluminum chalcogenide in the form of a tetracoordinate aluminum complex, (IMe 4 ) 2 (Tipp)Al=Te. This species reacts with three equivalents of CO 2 across two Al−C NHC and the Al=Te bond affording a pentacoordinate aluminum complex containing a dianionic tellurocarbonate ligand [CO 2 Te] 2− , which is the first example of tellurium analogue of a carbonate [CO 3 ] 2− ." @default.
- W4315750237 created "2023-01-13" @default.
- W4315750237 creator A5018318394 @default.
- W4315750237 creator A5028499877 @default.
- W4315750237 creator A5040440594 @default.
- W4315750237 creator A5067961961 @default.
- W4315750237 creator A5085608802 @default.
- W4315750237 date "2023-02-06" @default.
- W4315750237 modified "2023-10-14" @default.
- W4315750237 title "An Aluminum Telluride with a Terminal Al=Te Bond and its Conversion to an Aluminum Tellurocarbonate by CO<sub>2</sub> Reduction" @default.
- W4315750237 cites W108686929 @default.
- W4315750237 cites W1594126536 @default.
- W4315750237 cites W1973292183 @default.
- W4315750237 cites W1981831753 @default.
- W4315750237 cites W1983627570 @default.
- W4315750237 cites W1987926586 @default.
- W4315750237 cites W1991217587 @default.
- W4315750237 cites W1992793577 @default.
- W4315750237 cites W2041430974 @default.
- W4315750237 cites W2041520536 @default.
- W4315750237 cites W2041783147 @default.
- W4315750237 cites W2042381963 @default.
- W4315750237 cites W2052153691 @default.
- W4315750237 cites W2059487058 @default.
- W4315750237 cites W2060283478 @default.
- W4315750237 cites W2060726784 @default.
- W4315750237 cites W2070990699 @default.
- W4315750237 cites W2071984604 @default.
- W4315750237 cites W2078680826 @default.
- W4315750237 cites W2083802018 @default.
- W4315750237 cites W2084195519 @default.
- W4315750237 cites W2088124671 @default.
- W4315750237 cites W2091031920 @default.
- W4315750237 cites W2091088540 @default.
- W4315750237 cites W2092376153 @default.
- W4315750237 cites W2092973318 @default.
- W4315750237 cites W2103618880 @default.
- W4315750237 cites W2107272713 @default.
- W4315750237 cites W2139728585 @default.
- W4315750237 cites W2142529660 @default.
- W4315750237 cites W2158809942 @default.
- W4315750237 cites W2168542043 @default.
- W4315750237 cites W2171093181 @default.
- W4315750237 cites W2171914366 @default.
- W4315750237 cites W2196628743 @default.
- W4315750237 cites W2328061945 @default.
- W4315750237 cites W2329016702 @default.
- W4315750237 cites W2340045389 @default.
- W4315750237 cites W2362021544 @default.
- W4315750237 cites W2395952484 @default.
- W4315750237 cites W2413689003 @default.
- W4315750237 cites W2497296925 @default.
- W4315750237 cites W2514969807 @default.
- W4315750237 cites W2756328360 @default.
- W4315750237 cites W2765444819 @default.
- W4315750237 cites W2797749276 @default.
- W4315750237 cites W2803823325 @default.
- W4315750237 cites W2891530173 @default.
- W4315750237 cites W2910766786 @default.
- W4315750237 cites W2950560312 @default.
- W4315750237 cites W2951506868 @default.
- W4315750237 cites W2951669386 @default.
- W4315750237 cites W2952283590 @default.
- W4315750237 cites W2959654016 @default.
- W4315750237 cites W2975467184 @default.
- W4315750237 cites W3018975345 @default.
- W4315750237 cites W3032914644 @default.
- W4315750237 cites W3090189200 @default.
- W4315750237 cites W3109942202 @default.
- W4315750237 cites W3128515084 @default.
- W4315750237 cites W3157303750 @default.
- W4315750237 cites W3192004889 @default.
- W4315750237 cites W3194663249 @default.
- W4315750237 cites W3197477767 @default.
- W4315750237 cites W3201292144 @default.
- W4315750237 cites W3201487739 @default.
- W4315750237 cites W3215868511 @default.
- W4315750237 cites W4206117630 @default.
- W4315750237 cites W4206953901 @default.
- W4315750237 cites W4213009753 @default.
- W4315750237 cites W4225616591 @default.
- W4315750237 cites W4226419333 @default.
- W4315750237 cites W4238981217 @default.
- W4315750237 cites W4242662294 @default.
- W4315750237 cites W4245129989 @default.
- W4315750237 cites W4247799247 @default.
- W4315750237 cites W4250054509 @default.
- W4315750237 cites W4252617931 @default.
- W4315750237 cites W4255774850 @default.
- W4315750237 cites W4290015798 @default.
- W4315750237 cites W4367435819 @default.
- W4315750237 cites W4375905788 @default.
- W4315750237 doi "https://doi.org/10.1002/ange.202216021" @default.
- W4315750237 hasPublicationYear "2023" @default.
- W4315750237 type Work @default.
- W4315750237 citedByCount "0" @default.
- W4315750237 crossrefType "journal-article" @default.
- W4315750237 hasAuthorship W4315750237A5018318394 @default.
- W4315750237 hasAuthorship W4315750237A5028499877 @default.
- W4315750237 hasAuthorship W4315750237A5040440594 @default.