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- W4315781131 abstract "Heterobimetallic complexes featuring mesoionic carbene (MIC) donor ligands are gaining enormous popularity in tandem catalysis owing to the combined action of two different metal centers during catalysis. A rare version of the heterobimetallic PdII/IrIII complex possessing a cyclometalated mesoionic carbene (MIC) ligand is presented along with the analogous homodinuclear PdII complex. A sterically controlled regiospecific cyclometalation towards the formation of a six-membered ring complex over a five-membered ring complex has been performed using a naphthalene-based bis-MIC ligand platform. The interplay between regioselective vs. regiospecific C-H bond activation for the synthesis of cyclometalated IrIII complexes has also been demonstrated using the corresponding naphthyl-derived mono-imidazolylidene ligand. Both homodinuclear PdII and heterobimetallic PdII/IrIII complexes have been characterized using standard spectroscopic techniques including 1H, 13C{1H}, 2D correlation NMR spectroscopy and ESI mass spectrometry. The structure of the cyclometalated heterobimetallic complex has been established by single crystal XRD. The heterobimetallic complex has been employed as a pre-catalyst in the tandem Suzuki-Miyaura/transfer hydrogenation reaction and the homobimetallic PdII complex has been successfully employed as a catalyst in both the Sonogashira coupling and α-arylation of 1-methyl-2-oxindole." @default.
- W4315781131 created "2023-01-13" @default.
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- W4315781131 date "2023-01-01" @default.
- W4315781131 modified "2023-10-04" @default.
- W4315781131 title "A naphthalene-based heterobimetallic triazolylidene Ir<sup>III</sup>/Pd<sup>II</sup> complex: regioselective to regiospecific C–H activation, tandem catalysis and a copper-free Sonogashira reaction" @default.
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- W4315781131 doi "https://doi.org/10.1039/d2dt03508a" @default.
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