FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4315796000> ?p ?o ?g. }

• W4315796000 endingPage "171" @default.
• W4315796000 startingPage "171" @default.
• W4315796000 abstract "This study aims to examine the hydrodeoxygenation (HDO) of vanillin, an oxygenated phenolic compound present in bio-oil, into creosol. Biochar residue generated when wood is slowly pyrolyzed is utilized as a catalyst support. To improve biochar’s physicochemical properties, H2SO4 (sulfuric acid) and KOH (potassium hydroxide) are used as chemical activators. By means of a wet impregnation method with nickel salt, an Ni/biochar catalyst was prepared and utilized in the HDO of vanillin using a 100 mL Parr reactor, catalyst loading 0.4–0.8 g, temperature 100 °C to 150 °C, hydrogen (H2) pressures of 30 to 50 bar, and a stirring rate of 1000 rpm. The prepared catalysts were characterized with the nitrogen-sorption isotherm technique, carbon dioxide temperature-programmed desorption (CO2-TPD), scanning electron microscopy (SEM) coupled with energy dispersed X-ray analysis (EDX), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR). Based on chemical treatment, Ni/biochar (KOH) pore sizes were found to be dominated by mesopores, with a surface area increase of 64.7% and a volume increase of 65.3%, while Ni/biochar (H2SO4) was mostly microporous and mesoporous, with an area increase of 372.3% and a volume increase of 256.8% in comparison to Ni/biochar (74.84 m2g−1 and 0.095 cm3g−1). Vanillin conversion of up to 97% with 91.17% selectivity to p-creosol was obtained over Ni/biochar catalyst; in addition to being highly selective and active for p-creosol, a plausible fuel, the catalyst was stable after four cycles. Chemical treatments of the biochar support resulted in improved physicochemical properties, leading to improved catalytic performance in terms of vanillin conversion and p-creosol yield in the order Ni/biochar (H2SO4) > Ni/biochar (KOH) > Ni/biochar." @default.
• W4315796000 created "2023-01-13" @default.
• W4315796000 creator A5005192899 @default.
• W4315796000 creator A5083584072 @default.
• W4315796000 creator A5087516947 @default.
• W4315796000 creator A5090263847 @default.
• W4315796000 date "2023-01-11" @default.
• W4315796000 modified "2023-10-12" @default.
• W4315796000 title "Catalytic Hydrodeoxygenation of Vanillin, a Bio-Oil Model Compound over Renewable Ni/Biochar Catalyst" @default.
• W4315796000 cites W1913448811 @default.
• W4315796000 cites W1971326171 @default.
• W4315796000 cites W1975165411 @default.
• W4315796000 cites W1983602603 @default.
• W4315796000 cites W1986958696 @default.
• W4315796000 cites W1997811286 @default.
• W4315796000 cites W2033509028 @default.
• W4315796000 cites W2053680320 @default.
• W4315796000 cites W2053758882 @default.
• W4315796000 cites W2056542561 @default.
• W4315796000 cites W2060852319 @default.
• W4315796000 cites W2109293735 @default.
• W4315796000 cites W2403801044 @default.
• W4315796000 cites W2443198213 @default.
• W4315796000 cites W2511816494 @default.
• W4315796000 cites W2523765598 @default.
• W4315796000 cites W2542557069 @default.
• W4315796000 cites W2583015339 @default.
• W4315796000 cites W2604981346 @default.
• W4315796000 cites W2606321103 @default.
• W4315796000 cites W2781878791 @default.
• W4315796000 cites W2803334659 @default.
• W4315796000 cites W2805036884 @default.
• W4315796000 cites W2883111656 @default.
• W4315796000 cites W2888193827 @default.
• W4315796000 cites W2890476543 @default.
• W4315796000 cites W2904306482 @default.
• W4315796000 cites W2913921934 @default.
• W4315796000 cites W2920207465 @default.
• W4315796000 cites W2966388528 @default.
• W4315796000 cites W2972695732 @default.
• W4315796000 cites W2976234301 @default.
• W4315796000 cites W2982712945 @default.
• W4315796000 cites W2983292441 @default.
• W4315796000 cites W2985951212 @default.
• W4315796000 cites W3014677227 @default.
• W4315796000 cites W3025254135 @default.
• W4315796000 cites W3040083093 @default.
• W4315796000 cites W3043071541 @default.
• W4315796000 cites W3081685059 @default.
• W4315796000 cites W3097337717 @default.
• W4315796000 cites W3131665338 @default.
• W4315796000 cites W3134247485 @default.
• W4315796000 cites W3136052448 @default.
• W4315796000 cites W3136079408 @default.
• W4315796000 cites W3154196585 @default.
• W4315796000 cites W3155892176 @default.
• W4315796000 cites W3157827669 @default.
• W4315796000 cites W3158266839 @default.
• W4315796000 cites W3173375449 @default.
• W4315796000 cites W4213315496 @default.
• W4315796000 cites W4280580716 @default.
• W4315796000 cites W4292451643 @default.
• W4315796000 cites W899706182 @default.
• W4315796000 doi "https://doi.org/10.3390/catal13010171" @default.
• W4315796000 hasPublicationYear "2023" @default.
• W4315796000 type Work @default.
• W4315796000 citedByCount "1" @default.
• W4315796000 countsByYear W43157960002023 @default.
• W4315796000 crossrefType "journal-article" @default.
• W4315796000 hasAuthorship W4315796000A5005192899 @default.
• W4315796000 hasAuthorship W4315796000A5083584072 @default.
• W4315796000 hasAuthorship W4315796000A5087516947 @default.
• W4315796000 hasAuthorship W4315796000A5090263847 @default.
• W4315796000 hasBestOaLocation W43157960001 @default.
• W4315796000 hasConcept C118792377 @default.
• W4315796000 hasConcept C127413603 @default.
• W4315796000 hasConcept C13965031 @default.
• W4315796000 hasConcept C160892712 @default.
• W4315796000 hasConcept C161790260 @default.
• W4315796000 hasConcept C178790620 @default.
• W4315796000 hasConcept C179104552 @default.
• W4315796000 hasConcept C185592680 @default.
• W4315796000 hasConcept C192562407 @default.
• W4315796000 hasConcept C2777340834 @default.
• W4315796000 hasConcept C2778496505 @default.
• W4315796000 hasConcept C2779439175 @default.
• W4315796000 hasConcept C36759035 @default.
• W4315796000 hasConcept C42360764 @default.
• W4315796000 hasConcept C56085101 @default.
• W4315796000 hasConcept C82776694 @default.
• W4315796000 hasConceptScore W4315796000C118792377 @default.
• W4315796000 hasConceptScore W4315796000C127413603 @default.
• W4315796000 hasConceptScore W4315796000C13965031 @default.
• W4315796000 hasConceptScore W4315796000C160892712 @default.
• W4315796000 hasConceptScore W4315796000C161790260 @default.
• W4315796000 hasConceptScore W4315796000C178790620 @default.
• W4315796000 hasConceptScore W4315796000C179104552 @default.
• W4315796000 hasConceptScore W4315796000C185592680 @default.

• next