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- W4315928453 abstract "Electrochromic systems capable of switching near-infrared (NIR) absorption are fascinating from the viewpoint of applications in the materials and life sciences. Although 11,11,12,12-tetraaryl-9,10-anthraquinodimethanes (AQDs) with a folded form undergo one-stage two-electron oxidation to produce twisted dicationic dyes exhibiting NIR absorption, there is a need to establish a design strategy that can enhance the NIR-absorbing abilities of the corresponding dicationic dyes. In this study, we designed and synthesized a series of AQD derivatives with various substituents introduced at the ortho-position(s) of the 4-methoxyphenyl group. X-ray and spectroscopic analyses revealed that NIR-absorbing properties can be changed by introduction of the ortho-substituents. Thus, control of the steric and electronic effects of the ortho-substituents on the 4-methoxyphenyl groups was demonstrated to be an effective strategy for fine-tuning of the HOMO and LUMO levels for neutral AQDs and twisted dications, respectively, resulting in the modification of electrochemical and spectroscopic properties under an ortho-substitution strategy." @default.
- W4315928453 created "2023-01-14" @default.
- W4315928453 creator A5002456541 @default.
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- W4315928453 date "2023-03-16" @default.
- W4315928453 modified "2023-10-15" @default.
- W4315928453 title "Enhancement of NIR‐Absorbing Ability of Bis(diarylmethylium)‐Type Dicationic Dyes Based on an <i>Ortho</i>‐Substitution Strategy." @default.
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- W4315928453 doi "https://doi.org/10.1002/chem.202203899" @default.
- W4315928453 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36637412" @default.
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