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- W4316036005 abstract "Di-μ-chloro-bis[chloro(heptamethylindenyl)rhodium(III)], dichloro(heptamethylindenyl)rhodium(III) [171193-96-7] C32H42Cl2Rh2 (MW 778.308) (Rh) InChI = 1S/2C16H21.4ClH.2Rh/c2*1-8-9(2)12(5)16-14(7)10(3)13(6)15(16)11(8)4;;;;;;/h2*1-7H3;4*1H;;/q;;;;;;2*+2/p-4 InChIKey = SZHROYOIXDCEPT-UHFFFAOYSA-J (catalyst used for C(sp2)H activation and selective oxidation of alkene double bonds). Alternative Name(s): di-μ-chloro-bis[chloro(heptamethylindenyl)rhodium(III)], dichloro(heptamethyl-indenyl)rhodium(III), heptamethylindenyl rhodium dichloride dimer [Rh]. Physical Data: dark ruby crystalline solid. Solubility: soluble in chlorinated solvents (dichloromethane, dichloroethane, and chloroform), protic solvents (methanol, ethanol, iso-propanol, 1,1,1,3,3,3-hexafluoro-2-propanol, and 2,2,2-trifluoroethanol), and polar aprotic solvents (acetone, tetrahydrofuran, dimethylformamide, and dimethylsulfoxide); insoluble in water, diethyl ether, hexanes, and n-pentane. Form Supplied in: not commercially available. Form Synthesized as: rhodium dichloride dimer (solid). Analysis of Reagent Purity:1 1H NMR (400 MHz, CDCl3) δ [ppm] = 2.54 (s, 6H, 2 × CH3), 2.07 (s, 6H, 2 × CH3), 1.97 (s, 6H, 2 × CH3), 1.59 (s, 3H, CH3); 13C NMR (126 MHz, CDCl3) δ [ppm] = 143.7, 130.4, 102.6 (d), 95.2 (d), 81.0, 18.5, 17.8, 13.4, 10.3. Preparative Method: prepared from 1,2,3,4,5,6,7-heptamethylindene (Ind*H)2,3 and rhodium(III) chloride hydrate in refluxing ethanol.1,4,5 Purification: flash chromatography5 and/or recrystallization.4 Handling, Storage, and Precautions: air stable in the solid state." @default.
- W4316036005 created "2023-01-14" @default.
- W4316036005 creator A5087067186 @default.
- W4316036005 date "2023-01-13" @default.
- W4316036005 modified "2023-10-14" @default.
- W4316036005 title "Rhodium, Di‐μ‐chlorodichlorobis[(1,2,3,3 <i>a</i> ,7 <i>a</i> ‐η)‐1,2,3,4,5,6,7‐heptamethyl‐1 <i>H</i> ‐inden‐1‐yl]di‐, Stereoisomer (9CI)" @default.
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- W4316036005 doi "https://doi.org/10.1002/047084289x.rn02486" @default.
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