FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4316496632> ?p ?o ?g. }

• W4316496632 abstract "Abstract The new thiostannate Na 4 Sn 2 S 6 was prepared by directed crystal water removal from the hydrate Na 4 Sn 2 S 6 ⋅ 5H 2 O at moderate temperatures. While the structure of the hydrate comprises isolated [Sn 2 S 6 ] 4− anions, that of the anhydrate contains linear chains composed of corner‐sharing SnS 4 tetrahedra, a structural motif not known in thiostannate chemistry. This structural rearrangement requires bond‐breakage in the [Sn 2 S 6 ] 4− anion, movements of the fragments of the opened [Sn 2 S 6 ] 4− anion and Sn−S−Sn bond formation. Simultaneously, the coordination environment of the Na + cations is significantly altered and the in situ formed NaS 5 polyhedra are joined by corner‐ and edge‐sharing to form a six‐membered ring. Time‐dependent in situ X‐ray powder diffraction evidences very fast rehydration into Na 4 Sn 2 S 6 ⋅ 5H 2 O during storage in air atmosphere, but recovery of the initial crystallinity requires several days. Impedance spectroscopy demonstrates a mediocre room‐temperature Na + ion conductivity of 0.31 μS cm −1 and an activation energy for ionic transport of E a =0.75 eV." @default.
• W4316496632 created "2023-01-16" @default.
• W4316496632 creator A5018424043 @default.
• W4316496632 creator A5040153862 @default.
• W4316496632 creator A5046099728 @default.
• W4316496632 creator A5069621638 @default.
• W4316496632 creator A5076470331 @default.
• W4316496632 creator A5090811670 @default.
• W4316496632 date "2023-01-27" @default.
• W4316496632 modified "2023-09-26" @default.
• W4316496632 title "Directed Dehydration of Na₄Sn₂S₆ ⋅ 5H₂O Generates the New Compound Na₄Sn₂S₆: Crystal Structure and Selected Properties" @default.
• W4316496632 cites W1491785704 @default.
• W4316496632 cites W1965512320 @default.
• W4316496632 cites W1967287155 @default.
• W4316496632 cites W1971141052 @default.
• W4316496632 cites W1984446330 @default.
• W4316496632 cites W1985474962 @default.
• W4316496632 cites W1990575811 @default.
• W4316496632 cites W1994301296 @default.
• W4316496632 cites W2017307799 @default.
• W4316496632 cites W2036118996 @default.
• W4316496632 cites W2049344568 @default.
• W4316496632 cites W2051201657 @default.
• W4316496632 cites W2065131137 @default.
• W4316496632 cites W2070175377 @default.
• W4316496632 cites W2070307923 @default.
• W4316496632 cites W2072078803 @default.
• W4316496632 cites W2076257851 @default.
• W4316496632 cites W2080609422 @default.
• W4316496632 cites W2084526051 @default.
• W4316496632 cites W2091097318 @default.
• W4316496632 cites W2094222516 @default.
• W4316496632 cites W2102872073 @default.
• W4316496632 cites W2108248445 @default.
• W4316496632 cites W2164823173 @default.
• W4316496632 cites W2167590372 @default.
• W4316496632 cites W2189768581 @default.
• W4316496632 cites W2194855946 @default.
• W4316496632 cites W2287995244 @default.
• W4316496632 cites W2301215934 @default.
• W4316496632 cites W2340047421 @default.
• W4316496632 cites W2380221673 @default.
• W4316496632 cites W2418684137 @default.
• W4316496632 cites W2512434287 @default.
• W4316496632 cites W2526261209 @default.
• W4316496632 cites W2559950826 @default.
• W4316496632 cites W2754934601 @default.
• W4316496632 cites W2762626900 @default.
• W4316496632 cites W2773713132 @default.
• W4316496632 cites W2783420034 @default.
• W4316496632 cites W2795907136 @default.
• W4316496632 cites W2888089936 @default.
• W4316496632 cites W2913763463 @default.
• W4316496632 cites W2939047505 @default.
• W4316496632 cites W2949252785 @default.
• W4316496632 cites W2950340124 @default.
• W4316496632 cites W2952117073 @default.
• W4316496632 cites W2952619618 @default.
• W4316496632 cites W2952739207 @default.
• W4316496632 cites W2953048573 @default.
• W4316496632 cites W2963739020 @default.
• W4316496632 cites W3003630508 @default.
• W4316496632 cites W3011322503 @default.
• W4316496632 cites W3041927563 @default.
• W4316496632 cites W3093686232 @default.
• W4316496632 cites W3131671484 @default.
• W4316496632 cites W3133364080 @default.
• W4316496632 cites W3175252647 @default.
• W4316496632 cites W3213176825 @default.
• W4316496632 cites W4205726323 @default.
• W4316496632 cites W4249421400 @default.
• W4316496632 cites W4281667720 @default.
• W4316496632 cites W4304014318 @default.
• W4316496632 doi "https://doi.org/10.1002/ejic.202200687" @default.
• W4316496632 hasPublicationYear "2023" @default.
• W4316496632 type Work @default.
• W4316496632 citedByCount "1" @default.
• W4316496632 countsByYear W43164966322023 @default.
• W4316496632 crossrefType "journal-article" @default.
• W4316496632 hasAuthorship W4316496632A5018424043 @default.
• W4316496632 hasAuthorship W4316496632A5040153862 @default.
• W4316496632 hasAuthorship W4316496632A5046099728 @default.
• W4316496632 hasAuthorship W4316496632A5069621638 @default.
• W4316496632 hasAuthorship W4316496632A5076470331 @default.
• W4316496632 hasAuthorship W4316496632A5090811670 @default.
• W4316496632 hasBestOaLocation W43164966321 @default.
• W4316496632 hasConcept C115624301 @default.
• W4316496632 hasConcept C145148216 @default.
• W4316496632 hasConcept C178790620 @default.
• W4316496632 hasConcept C185592680 @default.
• W4316496632 hasConcept C2182769 @default.
• W4316496632 hasConcept C2781060337 @default.
• W4316496632 hasConcept C46275449 @default.
• W4316496632 hasConcept C8010536 @default.
• W4316496632 hasConceptScore W4316496632C115624301 @default.
• W4316496632 hasConceptScore W4316496632C145148216 @default.
• W4316496632 hasConceptScore W4316496632C178790620 @default.
• W4316496632 hasConceptScore W4316496632C185592680 @default.
• W4316496632 hasConceptScore W4316496632C2182769 @default.
• W4316496632 hasConceptScore W4316496632C2781060337 @default.

• next