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• W4316653701 abstract "Room temperature liquid NaK alloy is a promising candidate for high performance metal batteries, due to its dendrite-free property and high energy density. However, its practical application is hindered by the high surface tension of liquid NaK, which causes difficulties in maintaining a stable contact with a current collector. Here, the authors demonstrate the extraordinary stable confinement of NaK alloy at room temperature by constructing a super-wetting substrate, which is based on highly dispersed cobalt-single-atom carbon nanoarrays. The developed liquid anode electrode prevented successfully the leakage of NaK alloy even in harsh stress (>5 MPa) or sharp shock conditions. The symmetric cells achieved ultra-long reversible plating/stripping cycling life in both Na-ion (>1010 hrs) and K-ion electrolytes (>4000 hrs) at 10 mA cm-2 /10 mAh cm-2 . Upon fitting with Na3 V2 (PO4 )3 , the NaK assembled full battery provided high energy density (332.6 kWh kg-1 ) and power density (11.05 kW kg-1 ) with excellent stability after >21600 cycles, which is the best value reported so far. The prepared pouch cell was able to drive a four-axis aircraft, demonstrating a great prospect in practical application. This work offers a new approach in the preparation of advanced dendrite-free liquid metal anodes with promising applications in electrochemical energy storage." @default.
• W4316653701 created "2023-01-17" @default.
• W4316653701 creator A5038154663 @default.
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• W4316653701 date "2023-01-16" @default.
• W4316653701 modified "2023-10-04" @default.
• W4316653701 title "Single‐Atom Metallophilic Sites for Liquid NaK Alloy Confinement toward Stable Alkali‐Metal Anodes" @default.
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• W4316653701 doi "https://doi.org/10.1002/advs.202206479" @default.
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• W4316653701 hasPublicationYear "2023" @default.
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