FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4317107460> ?p ?o ?g. }

• W4317107460 abstract "Abstract Organic light emitting diodes based on thermally activated delayed fluorescent (TADF) emitters with both high external quantum efficiency (EQE) and low efficiency roll‐off are under urgent pursuing. Three TADF emitters based on fluorene‐spiro‐acridine derivatives as donors are developed. Composing of rigid donor and acceptor, all emitters exhibit high PLQYs of 96–99%. Direct conjugation attached on acridine offers an enhanced reverse intersystem crossing ( k RISC ) in IA‐TRZ, while the extension via spiro‐junction accelerates the radiative decay rate ( k r ) in 2S‐TRZ and IT‐TRZ. Remarkably, all emitters enable high electroluminescent performance with EQE of 35.6% for 2S‐TRZ, 36.1% for IT‐TRZ and 32.0% for IA‐TRZ, respectively, and very high luminance of up to 100 000 cd m −2 . Surprisingly, 2S‐TRZ and IT‐TRZ that hold larger k r and smaller k RISC than that of IA‐TRZ exhibit more relieved efficiency roll‐off, indicating the significance of k r . More importantly, IT‐TRZ with a moderate k r and k RISC among these emitters shows the lowest roll‐off which demonstrates that the comprehensive consideration of all photophysical processes is important to attain excellent devices. It also emphasizes the molecular modulation method through side group that can induce elaborate control on decay channels for finely optimizing emitters. This study can provide a useful perspective in designing practical emitters." @default.
• W4317107460 created "2023-01-18" @default.
• W4317107460 creator A5005584958 @default.
• W4317107460 creator A5027687145 @default.
• W4317107460 creator A5049136184 @default.
• W4317107460 creator A5059274322 @default.
• W4317107460 creator A5060455917 @default.
• W4317107460 creator A5068811434 @default.
• W4317107460 creator A5089900071 @default.
• W4317107460 date "2023-01-17" @default.
• W4317107460 modified "2023-10-17" @default.
• W4317107460 title "Donor Extension on Spiro‐Acridine Enables Highly Efficient TADF‐OLEDs with Relieved Efficiency Roll‐Off" @default.
• W4317107460 cites W1965207322 @default.
• W4317107460 cites W2058709487 @default.
• W4317107460 cites W2127834786 @default.
• W4317107460 cites W2132525235 @default.
• W4317107460 cites W2150702843 @default.
• W4317107460 cites W2414796456 @default.
• W4317107460 cites W2478294658 @default.
• W4317107460 cites W2592066197 @default.
• W4317107460 cites W2765541058 @default.
• W4317107460 cites W2772460041 @default.
• W4317107460 cites W2898394313 @default.
• W4317107460 cites W2901845319 @default.
• W4317107460 cites W2940023407 @default.
• W4317107460 cites W2946748128 @default.
• W4317107460 cites W2950316540 @default.
• W4317107460 cites W2957546222 @default.
• W4317107460 cites W2961543086 @default.
• W4317107460 cites W3035296040 @default.
• W4317107460 cites W3047427073 @default.
• W4317107460 cites W3092177768 @default.
• W4317107460 cites W3093361367 @default.
• W4317107460 cites W3096769128 @default.
• W4317107460 cites W3104248909 @default.
• W4317107460 cites W3114188203 @default.
• W4317107460 cites W3122614230 @default.
• W4317107460 cites W3134485520 @default.
• W4317107460 cites W3136469897 @default.
• W4317107460 cites W3161209639 @default.
• W4317107460 cites W3169380652 @default.
• W4317107460 cites W3199520778 @default.
• W4317107460 cites W3203932821 @default.
• W4317107460 cites W4214673681 @default.
• W4317107460 cites W4220873392 @default.
• W4317107460 cites W4226430604 @default.
• W4317107460 cites W4226466682 @default.
• W4317107460 cites W4292677395 @default.
• W4317107460 doi "https://doi.org/10.1002/adfm.202211696" @default.
• W4317107460 hasPublicationYear "2023" @default.
• W4317107460 type Work @default.
• W4317107460 citedByCount "7" @default.
• W4317107460 countsByYear W43171074602023 @default.
• W4317107460 crossrefType "journal-article" @default.
• W4317107460 hasAuthorship W4317107460A5005584958 @default.
• W4317107460 hasAuthorship W4317107460A5027687145 @default.
• W4317107460 hasAuthorship W4317107460A5049136184 @default.
• W4317107460 hasAuthorship W4317107460A5059274322 @default.
• W4317107460 hasAuthorship W4317107460A5060455917 @default.
• W4317107460 hasAuthorship W4317107460A5068811434 @default.
• W4317107460 hasAuthorship W4317107460A5089900071 @default.
• W4317107460 hasConcept C120665830 @default.
• W4317107460 hasConcept C121332964 @default.
• W4317107460 hasConcept C150759737 @default.
• W4317107460 hasConcept C171250308 @default.
• W4317107460 hasConcept C178790620 @default.
• W4317107460 hasConcept C181500209 @default.
• W4317107460 hasConcept C184779094 @default.
• W4317107460 hasConcept C185592680 @default.
• W4317107460 hasConcept C192562407 @default.
• W4317107460 hasConcept C205507967 @default.
• W4317107460 hasConcept C26873012 @default.
• W4317107460 hasConcept C2776924795 @default.
• W4317107460 hasConcept C2779227376 @default.
• W4317107460 hasConcept C2779892579 @default.
• W4317107460 hasConcept C31625292 @default.
• W4317107460 hasConcept C33062035 @default.
• W4317107460 hasConcept C49040817 @default.
• W4317107460 hasConcept C73978554 @default.
• W4317107460 hasConcept C74902906 @default.
• W4317107460 hasConcept C75473681 @default.
• W4317107460 hasConcept C78434282 @default.
• W4317107460 hasConcept C91881484 @default.
• W4317107460 hasConceptScore W4317107460C120665830 @default.
• W4317107460 hasConceptScore W4317107460C121332964 @default.
• W4317107460 hasConceptScore W4317107460C150759737 @default.
• W4317107460 hasConceptScore W4317107460C171250308 @default.
• W4317107460 hasConceptScore W4317107460C178790620 @default.
• W4317107460 hasConceptScore W4317107460C181500209 @default.
• W4317107460 hasConceptScore W4317107460C184779094 @default.
• W4317107460 hasConceptScore W4317107460C185592680 @default.
• W4317107460 hasConceptScore W4317107460C192562407 @default.
• W4317107460 hasConceptScore W4317107460C205507967 @default.
• W4317107460 hasConceptScore W4317107460C26873012 @default.
• W4317107460 hasConceptScore W4317107460C2776924795 @default.
• W4317107460 hasConceptScore W4317107460C2779227376 @default.
• W4317107460 hasConceptScore W4317107460C2779892579 @default.
• W4317107460 hasConceptScore W4317107460C31625292 @default.
• W4317107460 hasConceptScore W4317107460C33062035 @default.
• W4317107460 hasConceptScore W4317107460C49040817 @default.

• next