Matches in SemOpenAlex for { <https://semopenalex.org/work/W4317384319> ?p ?o ?g. }
- W4317384319 endingPage "1874" @default.
- W4317384319 startingPage "1863" @default.
- W4317384319 abstract "Iron-catalyzed N-transfer by hydroxylamine-derived reagents has emerged as an appealing method for the straightforward synthesis of unprotected primary amines. Here, we studied the detailed reaction mechanism of the FePc-catalyzed aminofunctionalization of styrene with AcO-NH3OTf and PivO-NH3OTf by quantum chemical calculations and mass spectrometry experiments. An inner-sphere heterolytic N–O cleavage mechanism was proposed for the hydroxylamine activation. It affords an unprotected iron-amido species ([PcFeNH2]+), which has been detected by mass spectrometry. The iron-amido species acts as the active aminating intermediate and reacts with styrene to form a radical intermediate, followed by nucleophilic addition with methanol to generate the product. Electronic structure analysis revealed σ- and π-channels in the N-transfer process for the iron-amido species. This reported iron–nitrogen complex resembles the iron-oxo species to possess both σ- and π-channels, unveiling the mechanistic connections with iron-oxo chemistry." @default.
- W4317384319 created "2023-01-19" @default.
- W4317384319 creator A5021245755 @default.
- W4317384319 creator A5040498255 @default.
- W4317384319 creator A5061475645 @default.
- W4317384319 creator A5064842058 @default.
- W4317384319 creator A5066623745 @default.
- W4317384319 creator A5088833974 @default.
- W4317384319 date "2023-01-18" @default.
- W4317384319 modified "2023-10-09" @default.
- W4317384319 title "Mechanism and Reaction Channels of Iron-Catalyzed Primary Amination of Alkenes by Hydroxylamine Reagents" @default.
- W4317384319 cites W1598885552 @default.
- W4317384319 cites W1970152976 @default.
- W4317384319 cites W1970549136 @default.
- W4317384319 cites W1988091937 @default.
- W4317384319 cites W2002384424 @default.
- W4317384319 cites W2006895285 @default.
- W4317384319 cites W2007669322 @default.
- W4317384319 cites W2010439031 @default.
- W4317384319 cites W2011215428 @default.
- W4317384319 cites W2023271753 @default.
- W4317384319 cites W2026756252 @default.
- W4317384319 cites W2029556357 @default.
- W4317384319 cites W2032719166 @default.
- W4317384319 cites W2033117796 @default.
- W4317384319 cites W2033259173 @default.
- W4317384319 cites W2034816859 @default.
- W4317384319 cites W2040527989 @default.
- W4317384319 cites W2052808022 @default.
- W4317384319 cites W2068185427 @default.
- W4317384319 cites W2079935930 @default.
- W4317384319 cites W2082669308 @default.
- W4317384319 cites W2086957099 @default.
- W4317384319 cites W2091788586 @default.
- W4317384319 cites W2092157292 @default.
- W4317384319 cites W2097532911 @default.
- W4317384319 cites W2119547517 @default.
- W4317384319 cites W2143981217 @default.
- W4317384319 cites W2203507006 @default.
- W4317384319 cites W2211824843 @default.
- W4317384319 cites W2235833940 @default.
- W4317384319 cites W2302161594 @default.
- W4317384319 cites W2313134014 @default.
- W4317384319 cites W2327994729 @default.
- W4317384319 cites W2330381666 @default.
- W4317384319 cites W2539635553 @default.
- W4317384319 cites W2542278646 @default.
- W4317384319 cites W2558994027 @default.
- W4317384319 cites W2562174173 @default.
- W4317384319 cites W2588880232 @default.
- W4317384319 cites W2735208100 @default.
- W4317384319 cites W2737873258 @default.
- W4317384319 cites W2768248400 @default.
- W4317384319 cites W2794902314 @default.
- W4317384319 cites W2898493890 @default.
- W4317384319 cites W2904503380 @default.
- W4317384319 cites W2908452108 @default.
- W4317384319 cites W2910647558 @default.
- W4317384319 cites W2974318288 @default.
- W4317384319 cites W2990704233 @default.
- W4317384319 cites W2999871400 @default.
- W4317384319 cites W3006550406 @default.
- W4317384319 cites W3015907012 @default.
- W4317384319 cites W3026121095 @default.
- W4317384319 cites W3092958457 @default.
- W4317384319 cites W3111041314 @default.
- W4317384319 cites W3114760178 @default.
- W4317384319 cites W3122445055 @default.
- W4317384319 cites W3200686549 @default.
- W4317384319 cites W3202988407 @default.
- W4317384319 cites W3207770201 @default.
- W4317384319 cites W3213656697 @default.
- W4317384319 cites W4200219606 @default.
- W4317384319 cites W4210320504 @default.
- W4317384319 cites W4214850459 @default.
- W4317384319 cites W4280523132 @default.
- W4317384319 cites W4292607405 @default.
- W4317384319 doi "https://doi.org/10.1021/acscatal.2c06046" @default.
- W4317384319 hasPublicationYear "2023" @default.
- W4317384319 type Work @default.
- W4317384319 citedByCount "1" @default.
- W4317384319 countsByYear W43173843192023 @default.
- W4317384319 crossrefType "journal-article" @default.
- W4317384319 hasAuthorship W4317384319A5021245755 @default.
- W4317384319 hasAuthorship W4317384319A5040498255 @default.
- W4317384319 hasAuthorship W4317384319A5061475645 @default.
- W4317384319 hasAuthorship W4317384319A5064842058 @default.
- W4317384319 hasAuthorship W4317384319A5066623745 @default.
- W4317384319 hasAuthorship W4317384319A5088833974 @default.
- W4317384319 hasConcept C121332964 @default.
- W4317384319 hasConcept C1276947 @default.
- W4317384319 hasConcept C15920480 @default.
- W4317384319 hasConcept C161790260 @default.
- W4317384319 hasConcept C178790620 @default.
- W4317384319 hasConcept C178907741 @default.
- W4317384319 hasConcept C185592680 @default.
- W4317384319 hasConcept C198503264 @default.
- W4317384319 hasConcept C21951064 @default.