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- W4317426327 abstract "Silicones intrinsically have low surface free energy and therefore either primers or additives, which function as adhesion promoters, must be utilized in order for silicones to adhere to surfaces. Alkoxysilanes, which are typically added to promote adhesion in condensation curable silicones, function by chemically coupling the silicone network to the substrate providing a deformable interfacial layer. We have developed a new class of addition curable silicones that are self-priming. These bifunctional materials are only partly miscible in the silicone matrix and bloom to the surface upon curing. The interfacial layer is comprised of an entanglement of the condensed adhesion promoter and the silicone matrix. X-ray Photoelectron Spectroscopy confirmed that the adhesion promoter concentration was enhanced at the adherend interface after cure. Molecular simulations support the hypothesis that the adhesion promoter most likely bonds to a hydroxyl defect site on the metal. The effect of adhesion promoter incorporation upon the curing profile of the silicone has been determined using NMR Imaging." @default.
- W4317426327 created "2023-01-19" @default.
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- W4317426327 date "2023-01-19" @default.
- W4317426327 modified "2023-09-23" @default.
- W4317426327 title "A new class of adhesion promoters for addition curable silicone adhesives" @default.
- W4317426327 doi "https://doi.org/10.1201/9780429070709-6" @default.
- W4317426327 hasPublicationYear "2023" @default.
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