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- W4317433459 abstract "We describe herein a chemo- and regioselective cascade annulation between β-ketothioamides and diazo-substituted hypervalent iodine reagents under transition-metal-free and base-free conditions at room temperature. Thus, a divergent construction of fused-heterocyclic scaffold thiazolothiadiazoles has been achieved with the advantages of operational simplicity, scalability, broad substrate compatibility, and mild reaction conditions. This one-pot strategy not only avoids potential toxicity but also broadens the arsenal of synthetic methods to obtain fused N,S-heterocyclic frameworks." @default.
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- W4317433459 date "2023-01-19" @default.
- W4317433459 modified "2023-10-16" @default.
- W4317433459 title "Access to Functionalized Thiazolothiadiazoles via the Chemoselective Cascade Heteroannulation of Thioamides with Hypervalent Iodine Reagents" @default.
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- W4317433459 doi "https://doi.org/10.1021/acs.orglett.2c04223" @default.
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