Matches in SemOpenAlex for { <https://semopenalex.org/work/W4317436902> ?p ?o ?g. }
- W4317436902 endingPage "3187" @default.
- W4317436902 startingPage "3177" @default.
- W4317436902 abstract "Controlling the kinetic processes of self-assembly and switching their kinetic properties according to the changes in external environments are crucial concepts in the field of supramolecular polymers in water for biological and biomedical applications. Here we report a new self-assembling amphiphilic 4-aminoquinoline (4-AQ)-tetraphenylethene (TPE) conjugate that exhibits kinetically controllable stepwise self-assembly and has the ability of switching its kinetic nature in response to pH. The self-assembly process of the 4-AQ amphiphile comprises the formation of sphere-like nanoparticles, a transition to short nanofibers, and their growth to long nanofibers with ∼1 μm length scale at room temperature (RT). The timescale of the self-assembly process differs according to the pH-responsivity of the 4-AQ moiety in a weakly acidic to neutral pH range. Therefore, after aging for 24 h at RT, the 4-AQ amphiphile forms metastable short nanofibers at pH 5.5, while it forms thermodynamically favored long nanofibers at pH 7.4. Moreover, the modulation of nanofiber growth proceeding spontaneously at RT was achieved by switching the kinetic pathway through changing the pH between 7.4 and 5.5." @default.
- W4317436902 created "2023-01-19" @default.
- W4317436902 creator A5009317819 @default.
- W4317436902 creator A5021925167 @default.
- W4317436902 creator A5023940411 @default.
- W4317436902 creator A5068086547 @default.
- W4317436902 creator A5070041914 @default.
- W4317436902 creator A5084495215 @default.
- W4317436902 date "2023-01-01" @default.
- W4317436902 modified "2023-09-30" @default.
- W4317436902 title "Control of the stepwise self-assembly process of a pH-responsive amphiphilic 4-aminoquinoline-tetraphenylethene conjugate" @default.
- W4317436902 cites W1963696254 @default.
- W4317436902 cites W1965428778 @default.
- W4317436902 cites W1965803800 @default.
- W4317436902 cites W1966612713 @default.
- W4317436902 cites W1967453978 @default.
- W4317436902 cites W1971170761 @default.
- W4317436902 cites W1984327089 @default.
- W4317436902 cites W1987123647 @default.
- W4317436902 cites W1990232537 @default.
- W4317436902 cites W1992720382 @default.
- W4317436902 cites W1993159043 @default.
- W4317436902 cites W1993359082 @default.
- W4317436902 cites W1994486848 @default.
- W4317436902 cites W1999611683 @default.
- W4317436902 cites W2000155437 @default.
- W4317436902 cites W2000846699 @default.
- W4317436902 cites W2003049596 @default.
- W4317436902 cites W2006532602 @default.
- W4317436902 cites W2007278339 @default.
- W4317436902 cites W2013455144 @default.
- W4317436902 cites W2015889028 @default.
- W4317436902 cites W2017215270 @default.
- W4317436902 cites W2018357220 @default.
- W4317436902 cites W2025423528 @default.
- W4317436902 cites W2027685213 @default.
- W4317436902 cites W2033747393 @default.
- W4317436902 cites W2043748429 @default.
- W4317436902 cites W2066181296 @default.
- W4317436902 cites W2069830708 @default.
- W4317436902 cites W2072248018 @default.
- W4317436902 cites W2073795835 @default.
- W4317436902 cites W2090595154 @default.
- W4317436902 cites W2095849709 @default.
- W4317436902 cites W2096503214 @default.
- W4317436902 cites W2103084915 @default.
- W4317436902 cites W2104314842 @default.
- W4317436902 cites W2110196431 @default.
- W4317436902 cites W2119489638 @default.
- W4317436902 cites W2121425613 @default.
- W4317436902 cites W2121975809 @default.
- W4317436902 cites W2123019134 @default.
- W4317436902 cites W2131217697 @default.
- W4317436902 cites W2131447388 @default.
- W4317436902 cites W2140885403 @default.
- W4317436902 cites W2150804274 @default.
- W4317436902 cites W2152752851 @default.
- W4317436902 cites W2153358174 @default.
- W4317436902 cites W2161730711 @default.
- W4317436902 cites W2163352384 @default.
- W4317436902 cites W2163668642 @default.
- W4317436902 cites W2170864231 @default.
- W4317436902 cites W2228784587 @default.
- W4317436902 cites W2255780632 @default.
- W4317436902 cites W2261520118 @default.
- W4317436902 cites W2273277013 @default.
- W4317436902 cites W2286580437 @default.
- W4317436902 cites W2294447007 @default.
- W4317436902 cites W2312689801 @default.
- W4317436902 cites W2315191255 @default.
- W4317436902 cites W2323743643 @default.
- W4317436902 cites W2325506209 @default.
- W4317436902 cites W2330862899 @default.
- W4317436902 cites W2332323677 @default.
- W4317436902 cites W2391066200 @default.
- W4317436902 cites W2406913770 @default.
- W4317436902 cites W2478765927 @default.
- W4317436902 cites W2510725391 @default.
- W4317436902 cites W2561239809 @default.
- W4317436902 cites W2593353853 @default.
- W4317436902 cites W2598224385 @default.
- W4317436902 cites W2606989105 @default.
- W4317436902 cites W2614420344 @default.
- W4317436902 cites W2617252472 @default.
- W4317436902 cites W2636501113 @default.
- W4317436902 cites W2748417965 @default.
- W4317436902 cites W2753160453 @default.
- W4317436902 cites W2777263366 @default.
- W4317436902 cites W2795177879 @default.
- W4317436902 cites W2888107399 @default.
- W4317436902 cites W2889089637 @default.
- W4317436902 cites W2889502288 @default.
- W4317436902 cites W2889913341 @default.
- W4317436902 cites W2895119005 @default.
- W4317436902 cites W2898941413 @default.
- W4317436902 cites W2899432267 @default.
- W4317436902 cites W2904814936 @default.
- W4317436902 cites W2943989597 @default.