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- W4317503509 abstract "Abstract This study presents the correlation of thermal, morphological and melt rheological properties of poly(ethylene oxide)/poly(methyl acrylate) (PEO/PMA) blends and PEO/poly( n ‐butyl methacrylate) (PEO/PnBMA) blends. The miscibility and correlation of these properties were assessed through thermal analysis such as glass transition temperature ( T g ) and apparent melting temperature ( T m ), morphological study and melt rheological analysis of the blends. The results show that PEO/PMA blends are miscible as suggested by the number of T g values that follow the Fox equation and the development of homogeneous mixtures in the molten state ( T = 80 °C). On the other hand, PEO/PnBMA blends are immiscible as shown by the constancy of the T g values of PEO throughout the blend compositions. The immiscibility was confirmed by optical microscopy which shows the matrix‐droplet and co‐continuous morphologies (i.e. heterogeneous mixtures) in the PEO/PnBMA blends at T = 80 °C. Melt rheological properties of the immiscible PEO/PnBMA blends are affected by the blend compositions and show significant deviation from Maxwell behaviour. Conversely, the rheological properties of the miscible PEO/PMA blends show close to Maxwell behaviour. Hence, the correlation of thermal, morphological and melt rheological studies is discussed for both miscible and immiscible PEO/polyacrylate blends. © 2023 Society of Industrial Chemistry." @default.
- W4317503509 created "2023-01-20" @default.
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- W4317503509 date "2023-02-07" @default.
- W4317503509 modified "2023-10-14" @default.
- W4317503509 title "Correlation of thermal, morphological and melt rheological properties of miscible poly(ethylene oxide)/poly(methyl acrylate) and immiscible poly(ethylene oxide)/poly(<i>n</i>‐butyl methacrylate) blends" @default.
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- W4317503509 doi "https://doi.org/10.1002/pi.6502" @default.
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