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- W4317506857 abstract "Abstract Hydroisomerization and hydrocracking of octylcyclohexane (C 14 H 28 ) were performed over Pt and NiMoS‐supported catalysts, at 300 °C and 60 bar, with a molar H 2 to hydrocarbon ratio of 7 mol/mol. The feed, composed of 5 wt.% phenyloctane dissolved in n‐heptane, was initially hydrogenated in situ over a pre‐catalyst, Pt or NiMoS/Al 2 O 3 . The C 14 naphthene underwent isomerization and cracking under high hydrogen pressure over the bifunctional catalysts, whose acid function was represented by large‐pore zeolities (USY, Beta) or amorphous silica‐alumina (SA). For the Pt‐catalysts, Beta was slightly more active than USY. Both zeolites produced a similar product pattern. Sulfide catalysts were less well equilibrated than Pt ones and hence less active. They led to some over‐cracking, but the cracking selectivity of our naphthene reactant was much less sensitive to the metal‐acid balance than the cracking selectivity of n‐alkanes. The comparison of reactivity of octylcyclohexane with n‐hexadecane and perhydrophenanthrene is also discussed." @default.
- W4317506857 created "2023-01-20" @default.
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- W4317506857 date "2023-02-07" @default.
- W4317506857 modified "2023-09-25" @default.
- W4317506857 title "Hydrocracking of a Long Chain Alkyl‐Cycloalkane: Role of Porosity and Metal‐Acid Balance" @default.
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- W4317506857 doi "https://doi.org/10.1002/cctc.202201286" @default.
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