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• W4317599493 endingPage "471" @default.
• W4317599493 startingPage "345" @default.
• W4317599493 abstract "Engineered alkane dehydrohalogenases (HLDs) have been shown to effect transhalogenation. Pre-organization of geranyllinalool and its esters in a self-assembled cage has been shown to lead to a U-shaped foldamer, owing to a combination of hydrophobic and polar interactions between the substrate and the elements of the cage, as revealed by X-ray crystallography and nuclear magnetic resonance spectroscopy. Amplification of the electrophilicity of N-chlorosuccinimide by irradiation with visible light in the presence of an organic dye photocatalyst, in particular Methylene Green, has allowed chlorination of aromatics and heteroaromatics. High-level calculations have demonstrated poor correlation between the proton affinity, reactivity, and cation stability of a series of chlorinated ethenes and propenes towards HCl in the gas phase, possibly because of the concerted mechanism avoiding the formation of carbocations." @default.
• W4317599493 created "2023-01-21" @default.
• W4317599493 creator A5084478574 @default.
• W4317599493 date "2023-01-20" @default.
• W4317599493 modified "2023-10-12" @default.
• W4317599493 title "Addition Reactions: Polar Addition" @default.
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