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- W4317631159 abstract "Under acidic conditions and at high ionic strength or in the presence of templating species, 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS[Formula: see text] self-organizes into J-aggregates. In these species, the porphyrins align in a general edge-to-edge geometry, responsible for their peculiar optical properties. The self-assembling process is hierarchical, and the kinetics are strongly dependent on the mixing protocols. In the case of sigmoidal profiles, the kinetic data have been treated using a model proposed in the literature by R.F. Pasternack. Accordingly, an autocatalytic growth with the formation of an [Formula: see text]-mer of porphyrin units is the rate-determining step (RDS) leading to the eventual J-aggregates whose size spans from nano- up to the micro-scale. The impact of different experimental parameters, together with inorganic counter-anions, and various cationic and anionic species (organic anions, metal ions, porphyrins, and metal complexes) will be reviewed." @default.
- W4317631159 created "2023-01-21" @default.
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- W4317631159 date "2023-01-01" @default.
- W4317631159 modified "2023-10-08" @default.
- W4317631159 title "J-aggregates of 5,10,15,20-tetrakis(4-sulfonatophenyl)-porphyrin. An overview of the supramolecular self-assembling mechanism" @default.
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- W4317631159 doi "https://doi.org/10.1142/s1088424623500153" @default.
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