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- W4317754313 abstract "Different metal halide catalysts supported on a commercial active charcoal have been synthesized, activated, characterized and tested in glucose dehydration to 5-hydroxymethylfurfural using a biphasic water/methyl isobutyl ketone media. The influence of the cation nature (K+, Ca2+, Sr2+, Mg2+) and anion nature (F-, Cl-, Br-) on the catalytic performance of the solid is discussed in terms of glucose conversion, HMF yield and products selectivity. The activation of the impregnated catalysts results in a great diversity of active sites, such as Bronsted sites (carboxylic groups), basic sites (metal oxide), and Lewis acid site (Mn+). Their distribution within the samples determinates the resulting products and the final HMF yield." @default.
- W4317754313 created "2023-01-23" @default.
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- W4317754313 date "2023-11-01" @default.
- W4317754313 modified "2023-10-12" @default.
- W4317754313 title "Glucose dehydration reaction over metal halides supported on activated charcoal catalysts" @default.
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- W4317754313 doi "https://doi.org/10.1016/j.cattod.2023.01.019" @default.
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