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• W4318154198 abstract "The non-toxic metal halide-based perovskite materials can be a greener alternative to leadbased perovskites because of their stability and high-scale production. Herein, we have tuned the structural and photophysical behaviour of non-toxic halide-based perovskite CsSnCl₃ by forming a heterostructure with reduced graphene oxide (rGO) owing to its high carrier mobility and thermal conductivity. The crystal structure of CsSnCl₃ and CsSnCl₃/rGO heterostructure has been analyzed using the X-ray diffraction (XRD) technique which confirms the formation of a highly crystalline cubic phase. The high absorption behaviour of CsSnCl₃ and CsSnCl3/rGO can be clearly seen from the ultraviolet-visible (UV-vis) spectrum. A direct bandgap of 3.24 eV and 3.19 eV has been calculated from the Tauc plot for CsSnCl₃ and CsSnCl₃/rGO heterostructure respectively. The Photoluminescence (PL) plot shows a high quenching blue shift phenomenon in CsSnCl3/rGO heterostructure as compared to pristine CsSnCl3 material due to the faster separation and transfer of charges from photogenerated electron-hole pairs. Further, the surface morphology of CsSnCl₃ and rGO/CsSnCl₃ heterostructure has been noticed by utilizing the Field Emission Gun-Scanning Electron Microscope (FEG-SEM) representing a very good morphology of synthesized materials in which CsSnCl₃ comprises a granular kind of structure which is spread over the rGO sheet. This study suggests the tenability of structural and optical properties with enhancement in stability of pristine CsSnCl₃ by forming heterostructure with rGO for their future utility in highly stable, and efficient photovoltaic and optical devices." @default.
• W4318154198 created "2023-01-27" @default.
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• W4318154198 date "2023-03-10" @default.
• W4318154198 modified "2023-10-18" @default.
• W4318154198 title "Tuning the structural and photophysical behaviour of non-toxic CsSnCl3 using reduced graphene oxide for optoelectronic applications" @default.
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• W4318154198 doi "https://doi.org/10.1117/12.2648289" @default.
• W4318154198 hasPublicationYear "2023" @default.
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