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- W4318449266 abstract "Novel cobalt(III) complexes of N-confused porphyrin (5,10,15,20-tetrakis(penta-fluorophenyl)-2-aza-21-carbaporphyrin) and its 3,3[Formula: see text]-linked dimer, Co1 and Co2, were synthesized and their structures were elucidated by X-ray crystallographic analysis and NMR spectroscopy. The redox properties of the complexes were examined by electrochemical approaches, and the corresponding oxidized/reduced species were analyzed by spectroelectrochemistry and DFT calculations. Notably, due to the facile redox feature of the N-confused porphyrins, ligand-centered oxidative/reductive processes were assumed for Co1 and Co2 presumably as inferred from the spectral analyses. These results indicate the unique multi-electron reservoir capability of the metal complexes of the N-confused porphyrin dimer." @default.
- W4318449266 created "2023-01-30" @default.
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- W4318449266 date "2023-04-17" @default.
- W4318449266 modified "2023-10-14" @default.
- W4318449266 title "Redox properties of bis-cobalt(III) complex of 3,3′-linked <i>N</i>-confused porphyrin dimer with axial pyridine ligands" @default.
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- W4318449266 doi "https://doi.org/10.1142/s1088424623500281" @default.
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