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- W4318478003 abstract "The mixed heteroadamantanes Si6Ge4 and Si6Sn4 are readily accessible from Me2ECl2/Si2Cl6/cat. Cl- (4 × EMe2, 2 × SiCl2, 4 × Si-SiCl3 vertices; E = Ge, Sn). Different from Si6Ge4, two skeletal isomers are formed in the case of Si6Sn4. Site-selective SiCl3-methylation of Si6Ge4 was achieved, leaving the SiCl2 groups untouched." @default.
- W4318478003 created "2023-01-30" @default.
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- W4318478003 date "2023-01-01" @default.
- W4318478003 modified "2023-10-16" @default.
- W4318478003 title "Group IV heteroadamantanes: synthesis of Si<sub>6</sub>Sn<sub>4</sub> and site-selective derivatization of Si<sub>6</sub>Ge<sub>4</sub>" @default.
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- W4318478003 doi "https://doi.org/10.1039/d2cc06697a" @default.
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