Matches in SemOpenAlex for { <https://semopenalex.org/work/W4318668248> ?p ?o ?g. }
- W4318668248 endingPage "2313" @default.
- W4318668248 startingPage "2306" @default.
- W4318668248 abstract "(sp2)C-(sp2)C bond formation is one of the most utilitarian techniques in target synthesis and material and pharmaceutical production. Biaryls usually emerge with the coupling of aryl halides or pseudohalides and require the prepreparation of an organometallic reagent, which results in low efficiency and atomic economy. The classic Ullmann reactions could be adopted to directly synthesize biaryls from aromatic halides. However, the requirement of extremely high temperatures limits the usage of the methodology in manufacturing. At the same time, the mechanism triggers a wide debate between classic redox and redox reactions involving radicals. In this work, a bimetallic system was demonstrated, referring to stoichiometric copper powder in the presence of a catalytic amount of Pd(OAc)2, which contributed to delivering various symmetric/asymmetric (sp2)C-(sp2)C species. It has been proposed that the coupling process might be promoted via radicals produced by redox between Cu(0) and Pd(IV) species in the heating system. Increasing examples demonstrated the good tolerance of this method for aryl bromide among functional groups." @default.
- W4318668248 created "2023-02-01" @default.
- W4318668248 creator A5016038041 @default.
- W4318668248 creator A5017281141 @default.
- W4318668248 creator A5055812136 @default.
- W4318668248 creator A5074210987 @default.
- W4318668248 creator A5086389098 @default.
- W4318668248 date "2023-01-31" @default.
- W4318668248 modified "2023-10-18" @default.
- W4318668248 title "Copper Powder and Pd(II) Salts Triggered One-Pot Aromatic Halide Homocoupling via a Radical Pathway" @default.
- W4318668248 cites W1504639292 @default.
- W4318668248 cites W169534460 @default.
- W4318668248 cites W1964168966 @default.
- W4318668248 cites W1964484777 @default.
- W4318668248 cites W1967921564 @default.
- W4318668248 cites W1970373050 @default.
- W4318668248 cites W1970837937 @default.
- W4318668248 cites W1973216464 @default.
- W4318668248 cites W1986800945 @default.
- W4318668248 cites W1991445038 @default.
- W4318668248 cites W1992520966 @default.
- W4318668248 cites W2010717359 @default.
- W4318668248 cites W2016187188 @default.
- W4318668248 cites W2022254888 @default.
- W4318668248 cites W2026047733 @default.
- W4318668248 cites W2027982776 @default.
- W4318668248 cites W2033658682 @default.
- W4318668248 cites W2048094838 @default.
- W4318668248 cites W2050442697 @default.
- W4318668248 cites W2077140838 @default.
- W4318668248 cites W2078771835 @default.
- W4318668248 cites W2087377704 @default.
- W4318668248 cites W2088680805 @default.
- W4318668248 cites W2105229123 @default.
- W4318668248 cites W2106683044 @default.
- W4318668248 cites W2117123115 @default.
- W4318668248 cites W2134711611 @default.
- W4318668248 cites W2140372631 @default.
- W4318668248 cites W2158308479 @default.
- W4318668248 cites W2169771066 @default.
- W4318668248 cites W2269624142 @default.
- W4318668248 cites W2281620033 @default.
- W4318668248 cites W2341492713 @default.
- W4318668248 cites W2528394554 @default.
- W4318668248 cites W2801754334 @default.
- W4318668248 cites W2889946035 @default.
- W4318668248 cites W2913566826 @default.
- W4318668248 cites W2950996000 @default.
- W4318668248 cites W2951256632 @default.
- W4318668248 cites W3004428900 @default.
- W4318668248 cites W3179121244 @default.
- W4318668248 doi "https://doi.org/10.1021/acs.joc.2c02717" @default.
- W4318668248 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36719812" @default.
- W4318668248 hasPublicationYear "2023" @default.
- W4318668248 type Work @default.
- W4318668248 citedByCount "0" @default.
- W4318668248 crossrefType "journal-article" @default.
- W4318668248 hasAuthorship W4318668248A5016038041 @default.
- W4318668248 hasAuthorship W4318668248A5017281141 @default.
- W4318668248 hasAuthorship W4318668248A5055812136 @default.
- W4318668248 hasAuthorship W4318668248A5074210987 @default.
- W4318668248 hasAuthorship W4318668248A5086389098 @default.
- W4318668248 hasConcept C139066938 @default.
- W4318668248 hasConcept C144082473 @default.
- W4318668248 hasConcept C161790260 @default.
- W4318668248 hasConcept C171560689 @default.
- W4318668248 hasConcept C178790620 @default.
- W4318668248 hasConcept C185592680 @default.
- W4318668248 hasConcept C21951064 @default.
- W4318668248 hasConcept C2776300020 @default.
- W4318668248 hasConcept C2780263894 @default.
- W4318668248 hasConcept C2781076698 @default.
- W4318668248 hasConcept C40875361 @default.
- W4318668248 hasConcept C43411465 @default.
- W4318668248 hasConcept C48424934 @default.
- W4318668248 hasConcept C544778455 @default.
- W4318668248 hasConcept C55904794 @default.
- W4318668248 hasConcept C75473681 @default.
- W4318668248 hasConceptScore W4318668248C139066938 @default.
- W4318668248 hasConceptScore W4318668248C144082473 @default.
- W4318668248 hasConceptScore W4318668248C161790260 @default.
- W4318668248 hasConceptScore W4318668248C171560689 @default.
- W4318668248 hasConceptScore W4318668248C178790620 @default.
- W4318668248 hasConceptScore W4318668248C185592680 @default.
- W4318668248 hasConceptScore W4318668248C21951064 @default.
- W4318668248 hasConceptScore W4318668248C2776300020 @default.
- W4318668248 hasConceptScore W4318668248C2780263894 @default.
- W4318668248 hasConceptScore W4318668248C2781076698 @default.
- W4318668248 hasConceptScore W4318668248C40875361 @default.
- W4318668248 hasConceptScore W4318668248C43411465 @default.
- W4318668248 hasConceptScore W4318668248C48424934 @default.
- W4318668248 hasConceptScore W4318668248C544778455 @default.
- W4318668248 hasConceptScore W4318668248C55904794 @default.
- W4318668248 hasConceptScore W4318668248C75473681 @default.
- W4318668248 hasFunder F4320321001 @default.
- W4318668248 hasFunder F4320323021 @default.
- W4318668248 hasIssue "4" @default.
- W4318668248 hasLocation W43186682481 @default.