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• W4318672150 startingPage "8138" @default.
• W4318672150 abstract "Nanostructured air electrodes play a crucial role in improving the electrocatalytic activity of oxygen reduction and evolution reactions in solid oxide cells (SOCs). Herein, we report the fabrication of a nanostructured BaCoO3-decorated cation-deficient PrBa0.8Ca0.2Co2O5+δ (PBCC) air electrode via a combined modification and direct assembly approach. The modification approach endows the dual-phase air electrode with a large surface area and abundant oxygen vacancies. An intimate air electrode-electrolyte interface is in situ constructed with the formation of a catalytically active Co3O4 bridging layer via electrochemical polarization. The corresponding single cell exhibits a peak power density of 2.08 W cm-2, an electrolysis current density of 1.36 A cm-2 at 1.3 V, and a good operating stability at 750 °C for 100 h. This study provides insights into the rational design and facile utilization of an active and stable nanostructured air electrode of SOCs." @default.
• W4318672150 created "2023-02-01" @default.
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• W4318672150 date "2023-01-31" @default.
• W4318672150 modified "2023-10-17" @default.
• W4318672150 title "Ultrafine, Dual-Phase, Cation-Deficient PrBa_0.8Ca_0.2Co₂O_5+δ Air Electrode for Efficient Solid Oxide Cells" @default.
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• W4318672150 doi "https://doi.org/10.1021/acsami.2c21172" @default.
• W4318672150 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36719322" @default.
• W4318672150 hasPublicationYear "2023" @default.
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