Matches in SemOpenAlex for { <https://semopenalex.org/work/W4318754631> ?p ?o ?g. }
- W4318754631 endingPage "5048" @default.
- W4318754631 startingPage "5037" @default.
- W4318754631 abstract "The synthesis and detailed characterization of low-viscosity room-temperature ionic liquids (RTILs) and [BnPh3P]+ salts with the cyano(fluoro)borate anions [BF(CN)3]- (MFB), [BF2(CN)2]- (DFB), and [BF3(CN)]- as well as the new mixed-substituted anion [BFH(CN)2]- (FHB) is described. The RTILs with [EMIm]+ or [BMPL]+ as countercations were obtained in yields of up to 98% from readily available alkali metal salts and in high purities that allow application in electrochemical devices. Trends in thermal stability, melting and freezing behavior, density, electrochemical stability, dynamic viscosity, specific conductivity and ion diffusivity have been assessed and compared to those of the related tetracyanoborate- and cyano(hydrido)borate-RTILs. The crystal structure analysis of the [BnPh3P]+ salts of [BFn(CN)4-n]- (n = 0-4), [BHn(CN)4-n]- (n = 1-3) and [BFH(CN)2]- provided experimental access to anion volumina that together with ion molecular mass, electrostatic potential, shape and chemical stability have been correlated to physicochemical properties. In addition, the cytotoxicity of the [EMIm]+-ILs and potassium or sodium salts was studied." @default.
- W4318754631 created "2023-02-02" @default.
- W4318754631 creator A5001051737 @default.
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- W4318754631 creator A5065335088 @default.
- W4318754631 creator A5072747786 @default.
- W4318754631 date "2023-01-01" @default.
- W4318754631 modified "2023-10-18" @default.
- W4318754631 title "Cyano(fluoro)borate and cyano(hydrido)borate ionic liquids: low-viscosity ionic media for electrochemical applications" @default.
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