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- W4318757259 abstract "In the paper, we prepared a hydrogenated nanocrystalline diamond (NCD-H) film by the chemical vapor deposition (CVD) method. A variable degree of NCD-H surface destruction and surface graphitization was achieved by Ar ion bombardment using monoatomic beam (Ar+) and cluster ion beam (ArCIB). Bombardment with ArCIB manifests itself by the formation of a very thin altered layer on the surface of NCD-H accompanied by no Ar atoms embedded in the surface region. In contrast, bombardment with Ar+ beam leads to the creation of thicker, homogeneous altered layer characterized by dominating C sp2 hybridization, by the embedded Ar atoms, and by the reduced dimensions of diamond grains located near the surface of the samples. A combination of multiple microscopy and spectroscopy methods enabled us to evaluate the contribution of the C-Hx bonds to the asymmetry of the C 1s core level line shape and to measure the H concentration on the surface. The limitation of Auger spectroscopy (D-parameter) analysis for the sp2/sp3 phase concentration measurement on rough, NCD-H surface is demonstrated. The controllable amorphization or graphitization of diamond surface can further extend its functionality in detectors, electrochemical sensing or supercapacitor uses." @default.
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- W4318757259 date "2023-03-01" @default.
- W4318757259 modified "2023-10-14" @default.
- W4318757259 title "Effects of monoatomic and cluster bombardment with Ar ion beam on the surface of hydrogenated nanocrystalline diamond" @default.
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- W4318757259 doi "https://doi.org/10.1016/j.diamond.2023.109748" @default.
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