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- W4318766773 endingPage "7848" @default.
- W4318766773 startingPage "7844" @default.
- W4318766773 abstract "A highly regiospecific vinylogous carbene insertion protocol for direct asymmetric C–H functionalization of indoles with arylvinyldiazoacetates has been developed. Under the catalysis of simple Rh(I)/chiral diene complexes, the reaction occurs solely at the vinylogous position of the vinylcarbenoid with exceptional E selectivity and enantiocontrol. It provides an efficient way to obtain an interesting class of chiral indole scaffolds bearing an α,β-unsaturated ester unit and a gem-diaryl carbon stereocenter in good yields (≤99%) with excellent enantioselectivities (≤96%) at room temperature." @default.
- W4318766773 created "2023-02-02" @default.
- W4318766773 creator A5049975288 @default.
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- W4318766773 date "2023-02-01" @default.
- W4318766773 modified "2023-10-14" @default.
- W4318766773 title "Rhodium(I)-Catalyzed Direct Enantioselective C–H Functionalization of Indoles" @default.
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- W4318766773 doi "https://doi.org/10.1021/acs.joc.2c02624" @default.
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