Matches in SemOpenAlex for { <https://semopenalex.org/work/W4318940186> ?p ?o ?g. }
- W4318940186 endingPage "108257" @default.
- W4318940186 startingPage "108257" @default.
- W4318940186 abstract "Research and development of appropriate electrolytes have been deemed as the key for the commercial utilization of rechargeable magnesium batteries (RMBs) with high energy densities, especially for the storage systems containing high capacity cathode materials. In this study, the cost-competitive magnesium salt Mg(CF3SO3)2, which is structurally similar to Mg(TFSI)2, has been proved to possess stronger hydrophobic property, weaker reducibility and reactivity with Mg anodes by experimental comparison and calculation analysis, whereas limited self-generated oxidation resistance of the anion and inferior ionic conductivity in aprotic solvents restrain its practical application. Herein a small amount of PP14TFSI ionic liquid (IL) as multifunctional additive in Mg(CF3SO3)2-based electrolytes has been demonstrated comprehensive improvements in performance, including broadened electrochemical window, ameliorated ionic conductivity (∼6 mS cm−1), homogenization and optimization in interfacial flux and composition, and stable cycling reversibility with low polarization (0.11 V), etc. The IL tailored electrolytes also exhibit desirable compatibility with Mo6S8 (66.9 mAh g−1 after 100 cycles at 0.1 C) and Cu3Se2 (131.7 mAh g−1 after 100 cycles at 200 mAh g−1). Meanwhile, the nucleophilicity of CF3SO3- has been initially discussed on the basis of the cycling results of [email protected]||Mg ([email protected] carbon||Mg) and CuS||Mg full batteries. This work has deepened the understanding of Mg(CF3SO3)2 and IL in RMB electrolytes, and provided a new insight for the exploration of electrolyte systems based on simple magnesium salts." @default.
- W4318940186 created "2023-02-03" @default.
- W4318940186 creator A5002773536 @default.
- W4318940186 creator A5005448882 @default.
- W4318940186 creator A5020714359 @default.
- W4318940186 creator A5022802322 @default.
- W4318940186 creator A5049299709 @default.
- W4318940186 creator A5049692788 @default.
- W4318940186 creator A5062281451 @default.
- W4318940186 creator A5070673257 @default.
- W4318940186 creator A5079656901 @default.
- W4318940186 creator A5084303118 @default.
- W4318940186 creator A5090652507 @default.
- W4318940186 date "2023-05-01" @default.
- W4318940186 modified "2023-10-05" @default.
- W4318940186 title "Deeping insight of Mg(CF3SO3)2 and comprehensive modified electrolyte with ionic liquid enabling high-performance magnesium batteries" @default.
- W4318940186 cites W1983957774 @default.
- W4318940186 cites W1999906396 @default.
- W4318940186 cites W1999955543 @default.
- W4318940186 cites W2041815411 @default.
- W4318940186 cites W2044915653 @default.
- W4318940186 cites W2064391824 @default.
- W4318940186 cites W2066517183 @default.
- W4318940186 cites W2081235448 @default.
- W4318940186 cites W2137205422 @default.
- W4318940186 cites W2146317650 @default.
- W4318940186 cites W2152502531 @default.
- W4318940186 cites W2197754192 @default.
- W4318940186 cites W2233799421 @default.
- W4318940186 cites W2260342793 @default.
- W4318940186 cites W2281490883 @default.
- W4318940186 cites W2328210275 @default.
- W4318940186 cites W2491559270 @default.
- W4318940186 cites W2550054916 @default.
- W4318940186 cites W2553145141 @default.
- W4318940186 cites W2599156484 @default.
- W4318940186 cites W2604754163 @default.
- W4318940186 cites W2607570316 @default.
- W4318940186 cites W2750288193 @default.
- W4318940186 cites W2753669865 @default.
- W4318940186 cites W2760250892 @default.
- W4318940186 cites W2795488720 @default.
- W4318940186 cites W2795577707 @default.
- W4318940186 cites W2883630045 @default.
- W4318940186 cites W2885622823 @default.
- W4318940186 cites W2900574166 @default.
- W4318940186 cites W2902124156 @default.
- W4318940186 cites W2907985102 @default.
- W4318940186 cites W2914103247 @default.
- W4318940186 cites W2927611596 @default.
- W4318940186 cites W2935776135 @default.
- W4318940186 cites W2942968888 @default.
- W4318940186 cites W2981795899 @default.
- W4318940186 cites W2991833799 @default.
- W4318940186 cites W2995349791 @default.
- W4318940186 cites W3003477077 @default.
- W4318940186 cites W3012598876 @default.
- W4318940186 cites W3015646816 @default.
- W4318940186 cites W3031972302 @default.
- W4318940186 cites W3044463207 @default.
- W4318940186 cites W3083919358 @default.
- W4318940186 cites W3093543867 @default.
- W4318940186 cites W3128753104 @default.
- W4318940186 cites W3159432967 @default.
- W4318940186 cites W3162846423 @default.
- W4318940186 cites W3175199915 @default.
- W4318940186 cites W3175509387 @default.
- W4318940186 cites W3181011415 @default.
- W4318940186 cites W3186071258 @default.
- W4318940186 cites W3187481426 @default.
- W4318940186 cites W4200552216 @default.
- W4318940186 cites W4246564050 @default.
- W4318940186 cites W4303496165 @default.
- W4318940186 doi "https://doi.org/10.1016/j.nanoen.2023.108257" @default.
- W4318940186 hasPublicationYear "2023" @default.
- W4318940186 type Work @default.
- W4318940186 citedByCount "5" @default.
- W4318940186 countsByYear W43189401862023 @default.
- W4318940186 crossrefType "journal-article" @default.
- W4318940186 hasAuthorship W4318940186A5002773536 @default.
- W4318940186 hasAuthorship W4318940186A5005448882 @default.
- W4318940186 hasAuthorship W4318940186A5020714359 @default.
- W4318940186 hasAuthorship W4318940186A5022802322 @default.
- W4318940186 hasAuthorship W4318940186A5049299709 @default.
- W4318940186 hasAuthorship W4318940186A5049692788 @default.
- W4318940186 hasAuthorship W4318940186A5062281451 @default.
- W4318940186 hasAuthorship W4318940186A5070673257 @default.
- W4318940186 hasAuthorship W4318940186A5079656901 @default.
- W4318940186 hasAuthorship W4318940186A5084303118 @default.
- W4318940186 hasAuthorship W4318940186A5090652507 @default.
- W4318940186 hasConcept C127413603 @default.
- W4318940186 hasConcept C131540310 @default.
- W4318940186 hasConcept C138679309 @default.
- W4318940186 hasConcept C147789679 @default.
- W4318940186 hasConcept C152520256 @default.
- W4318940186 hasConcept C154881586 @default.
- W4318940186 hasConcept C161790260 @default.
- W4318940186 hasConcept C17525397 @default.