FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4318958049> ?p ?o ?g. }

• W4318958049 endingPage "16592" @default.
• W4318958049 startingPage "16569" @default.
• W4318958049 abstract "The increasing global energy demand has resulted in consumption of fossil fuel-based resources at a rapid rate. This has led to depletion of the fossil fuels at a faster rate and in addition, the toxic gases produced on burning of fossil fuels have caused a serious impact on environment. Owing to the fulfillment of energy demand for sustainable development, it is of paramount importance to focus and develop renewable energy sources as major energy supply chain. Hence, lot of efforts has been put in the development of environment friendly, safe, cost-effective, and reliable renewable energy storage and conversion systems. Among the various alternative energy systems, the electrochemical energy devices like proton exchange membrane fuel cells are of major concern as they provide continuous energy with high energy density, easy transportation, portable devices with clean and green energy. These Fuel cells need a fuel and an oxidant to produce the electrical energy. The molecular hydrogen (H2) is a prominent clean and green renewable energy source which is used as an efficient fuel in fuel cell devices. Out of various methods of H2 production, water splitting reaction has clinched much attention as it is an efficient method for H2 production and does not involve the release of any carbon footprints to atmosphere. However, the sluggish kinetics of hydrogen evolution reaction (HER) at the cathode is one of the major limitations in water electrolyzer and in addition, precious and less abundant Pt is employed as catalyst at cathode which hinders the commercialization of the fuel cells. In this context, the design and development of efficient, cost effective and durable electrocatalyst material for HER is a biggest challenge. Among the various types of catalytic materials, N-4 macrocycle derived catalysts namely, phthalocyanines have been recognized as potential cathode electrocatalysts for improving the reaction kinetics of the HER. This review highlights the advantages of phthalocyanine based catalysts over other metal-based catalysts and presents recent developments in MPc based electrocatalysts for the HER. The review gives brief introduction to the fundamentals and reaction mechanism of HER activity. The dependence of HER activity on the electrolyte and pH are discussed. An elaborative description has been provided on different kinds of electrocatalysts employed for HER including noble metal catalysts and non-precious as well as carbon based electrocatalysts. Furthermore, an emphasis has been provided on the N-4 macrocycles, particularly MPc based materials including introduction to MPcs, potential properties and advantages for HER activity. Various experimental parameters like catalytic activity and long-term stability of the MPc based electrode materials have been considered. At the end, summary and outlook as well as future challenges of MPc complex materials have been discussed." @default.
• W4318958049 created "2023-02-03" @default.
• W4318958049 creator A5024551600 @default.
• W4318958049 creator A5069332807 @default.
• W4318958049 creator A5088306648 @default.
• W4318958049 date "2023-05-01" @default.
• W4318958049 modified "2023-10-06" @default.
• W4318958049 title "Developments in electrocatalysts for electrocatalytic hydrogen evolution reaction with reference to bio-inspired phthalocyanines" @default.
• W4318958049 cites W1696716371 @default.
• W4318958049 cites W1734768115 @default.
• W4318958049 cites W1749142774 @default.
• W4318958049 cites W1969528771 @default.
• W4318958049 cites W1969923626 @default.
• W4318958049 cites W1974267403 @default.
• W4318958049 cites W1974426099 @default.
• W4318958049 cites W1976854186 @default.
• W4318958049 cites W1979187276 @default.
• W4318958049 cites W1980317218 @default.
• W4318958049 cites W1984552733 @default.
• W4318958049 cites W1989205080 @default.
• W4318958049 cites W1989715071 @default.
• W4318958049 cites W1990130563 @default.
• W4318958049 cites W1991426583 @default.
• W4318958049 cites W1991470376 @default.
• W4318958049 cites W1998493928 @default.
• W4318958049 cites W2008425077 @default.
• W4318958049 cites W2010780117 @default.
• W4318958049 cites W2012136380 @default.
• W4318958049 cites W2015127275 @default.
• W4318958049 cites W2018624132 @default.
• W4318958049 cites W2031671421 @default.
• W4318958049 cites W2034291571 @default.
• W4318958049 cites W2038218659 @default.
• W4318958049 cites W2038326351 @default.
• W4318958049 cites W2043775186 @default.
• W4318958049 cites W2050104692 @default.
• W4318958049 cites W2050833870 @default.
• W4318958049 cites W2052897845 @default.
• W4318958049 cites W2058916144 @default.
• W4318958049 cites W2061447936 @default.
• W4318958049 cites W2064667030 @default.
• W4318958049 cites W2065018748 @default.
• W4318958049 cites W2075073144 @default.
• W4318958049 cites W2076154302 @default.
• W4318958049 cites W2077979133 @default.
• W4318958049 cites W2084077391 @default.
• W4318958049 cites W2086090636 @default.
• W4318958049 cites W2086324139 @default.
• W4318958049 cites W2086403734 @default.
• W4318958049 cites W2086578423 @default.
• W4318958049 cites W2087059155 @default.
• W4318958049 cites W2091718794 @default.
• W4318958049 cites W2092973850 @default.
• W4318958049 cites W2101317526 @default.
• W4318958049 cites W2102333114 @default.
• W4318958049 cites W2103308798 @default.
• W4318958049 cites W2109957556 @default.
• W4318958049 cites W2114572722 @default.
• W4318958049 cites W2118564549 @default.
• W4318958049 cites W2118976774 @default.
• W4318958049 cites W2120124901 @default.
• W4318958049 cites W2137776484 @default.
• W4318958049 cites W2145646973 @default.
• W4318958049 cites W2160151078 @default.
• W4318958049 cites W2192777122 @default.
• W4318958049 cites W2202125076 @default.
• W4318958049 cites W2206856403 @default.
• W4318958049 cites W2216081842 @default.
• W4318958049 cites W2268645077 @default.
• W4318958049 cites W2274258295 @default.
• W4318958049 cites W2274291878 @default.
• W4318958049 cites W2282578395 @default.
• W4318958049 cites W2301020269 @default.
• W4318958049 cites W2317684707 @default.
• W4318958049 cites W2329971220 @default.
• W4318958049 cites W2331668115 @default.
• W4318958049 cites W2333208427 @default.
• W4318958049 cites W2333661106 @default.
• W4318958049 cites W2334744611 @default.
• W4318958049 cites W2411987129 @default.
• W4318958049 cites W2472879114 @default.
• W4318958049 cites W2497948683 @default.
• W4318958049 cites W2520275386 @default.
• W4318958049 cites W2520444078 @default.
• W4318958049 cites W2520657555 @default.
• W4318958049 cites W2521341169 @default.
• W4318958049 cites W2544993282 @default.
• W4318958049 cites W2549149855 @default.
• W4318958049 cites W2556233507 @default.
• W4318958049 cites W2560622252 @default.
• W4318958049 cites W2605024271 @default.
• W4318958049 cites W2608370037 @default.
• W4318958049 cites W2613728987 @default.
• W4318958049 cites W2735868127 @default.
• W4318958049 cites W2744118444 @default.
• W4318958049 cites W2748478263 @default.
• W4318958049 cites W2751572254 @default.
• W4318958049 cites W2764137116 @default.

• next