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- W4319078712 abstract "The development of repairable MOF-polymer hybrid materials will greatly extend their service life by repairing fractured parts on the spot; however, it is difficult for robust glassy polymers to self-heal below the glass transition temperature (Tg) as the polymer network is frozen. We herein report glassy polyMOF-RHP hybrid membranes by integrating lanthanide polyMOF (polyLnMOF) with randomly hyperbranched polymers (RHP) bearing a high density of hydrogen bonds. Since crystalline lanthanide MOFs act as multiconnected cross-linking agents and cross-link the interpenetrating polymer network, the obtained polyLnMOF-polymer membrane shows enhanced mechanical strength with a storage modulus of 3.09 GPa and a Tg up to 49 °C. Meanwhile, the high intersegment migration ability of the polyLnMOF-polymer network facilitates the exchange of hydrogen-bonded pairs even in the glassy state, leading to an instantaneous room-temperature self-healing ability. The polyLnMOF-polymer membranes inherit the ratiometric temperature-sensing behavior of pristine lanthanide MOFs, resulting in more processable temperature-sensing membranes. This work provides an appealing strategy for the design of mechanically robust, yet self-healing, MOF-polymer functional materials." @default.
- W4319078712 created "2023-02-04" @default.
- W4319078712 creator A5027577465 @default.
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- W4319078712 creator A5076409244 @default.
- W4319078712 date "2023-01-01" @default.
- W4319078712 modified "2023-10-18" @default.
- W4319078712 title "A rapid self-healing glassy polymer/metal–organic-framework hybrid membrane at room temperature" @default.
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- W4319078712 doi "https://doi.org/10.1039/d2dt03926e" @default.
- W4319078712 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36790126" @default.
- W4319078712 hasPublicationYear "2023" @default.
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