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- W4319232176 abstract "In this work, a sol-gel Ni–Mo2C–Al2O3 catalyst is employed for the first time in the glycerol steam reforming for syngas production. Catalyst stability and activity are investigated in the temperature range of 550 °C–700 °C and time on stream up to 30 h. As reaction temperature increases, from 550 °C to 700 °C, H2 yield boosts from 22% to 60%. The stability test, carried out at milder conditions (600 °C and Gas-Hourly Space-Velocity (GHSV) of 50,000 mL h−1.gcat−1), shows high catalyst stability, up to 30 h, with final conversion, H2 yield, and H2/CO ratio of 95%, 53% and 1.95, respectively. Both virgin and spent catalysts have been characterized by a multitude of techniques, e.g., Atomic-Absorption spectroscopy, Raman spectroscopy, N2-adsorption-desorption, and Transmission Electron Microscopy (TEM), among others. Regarding the spent catalysts, carbon deposits’ morphology becomes more graphitic as the reaction temperature increases, and the total coke formation is mitigated by increasing reaction temperature and lowering GHSV." @default.
- W4319232176 created "2023-02-05" @default.
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- W4319232176 date "2023-05-01" @default.
- W4319232176 modified "2023-10-16" @default.
- W4319232176 title "Turning glycerol surplus into renewable syngas through glycerol steam reforming over a sol-gel Ni–Mo2C-Al2O3 catalyst" @default.
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- W4319232176 doi "https://doi.org/10.1016/j.ijhydene.2023.01.166" @default.
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