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- W4319302470 abstract "Sintering behaviorSintering behavior was vitally significant for lubrication and heat transfer performance of mold fluxes during a casting process. In this paper, sintering behaviorSintering behavior of CaO–SiO2–Al2O3–CaF2CaF slags system was systematically investigated by combining with TG-DSC, XRD, DIL, and SEM techniques. The mineral phase transformation process of slags was clearly understood during the heating process. A brand-new evaluation method from volume shrinkageVolume shrinkage was adopted to investigate the sintering behaviorSintering behavior. The results showed that Ca2SiO4 was formed at 1370 °C in CaO–SiO2 slags with 12.63% volume shrinkage. Ca4Si2O7F2 was occurred at 1173 °C with 64.06% volume shrinkageVolume shrinkage of slags while CaF2CaF was added to CaO–SiO2 slags. In CaO–SiO2–Al2O3 slags, Ca3Al2O6 was first formed and then transformed into Ca2Al2SiO7 at 1342 °C with 53.63% volume shrinkage. At 1148 °C, the Ca2Al2SiO7 and Ca4Si2O7F2 coexisted in CaO–SiO2–Al2O3–CaF2 slags with the volume shrinkageVolume shrinkage of 60.13%. The solid phase reactionSolid phase reaction temperatures of slags were decreased by adding CaF2CaF and Al2O3AlO, caused by the attenuation of the bonding energy between Si–O in molten slag structure. SEM results expounded that during the sintering process, the structure of sample changed from loose to dense, new crystals produced, and crystal transformation behavior was conducted, Thus, all leading to the volume shrinkageVolume shrinkage behavior." @default.
- W4319302470 created "2023-02-07" @default.
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- W4319302470 date "2023-01-01" @default.
- W4319302470 modified "2023-09-23" @default.
- W4319302470 title "A Comprehensive Investigation on the Sintering Behavior of CaO–SiO2–CaF2–Al2O3 Slags System" @default.
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- W4319302470 doi "https://doi.org/10.1007/978-3-031-22524-6_124" @default.
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