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- W4319303485 abstract "Here, we developed three different amorphous structural designs of Mn nanomaterials (nanospheres, nanoflowers, and nanopetals) electrostatically coupled with the gold nanostructures (GNRs and GNSs) to improve their efficiency for photoreduction of CO2 to HCOOH and Suzuki-Miyaura coupling reaction in full-spectrum. The gold nanorods (GNRs) decorated Mn nanopetals ([email protected]) showed high efficacy for CO2 reduction to HCOOH with 2.24% of quantum yield and 3.79% of chemical yield in visible light irradiation (6.0 W/cm2) at room temperature. The [email protected] exhibited impressive yield for HCOOH formation in NIR and sunlight irradiation too. Likewise, the [email protected] showed excellent efficiency for the Suzuki-Miyaura coupling reaction with 99.41% of biphenyl yield in visible light irradiation for 2.0 h at 50 °C. At room temperature (25 °C) the photocatalyst showed 58.71% of biphenyl yield in visible light irradiation. The [email protected] exhibited great activity for ten recycles for CO2 conversion as well as coupling reaction without losing activity." @default.
- W4319303485 created "2023-02-07" @default.
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- W4319303485 date "2023-04-01" @default.
- W4319303485 modified "2023-09-30" @default.
- W4319303485 title "Deciphering Au-manganese oxide nanopetals plasmon–exciton co-driven artificial photosynthesis and Suzuki-Miyaura coupling reactions" @default.
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- W4319303485 doi "https://doi.org/10.1016/j.mtener.2023.101261" @default.
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