Matches in SemOpenAlex for { <https://semopenalex.org/work/W4319333012> ?p ?o ?g. }
- W4319333012 abstract "A series of helically shaped benzo[b]chryseno[4,3-d]thiophenes, naphtho[1,2-b]phenanthro[4,3-d]thiophenes, and chryseno[3,4-b]naphtho[1,2-d]thiophenes is synthesized via a highly enantioselective Au-catalyzed intramolecular alkyne hydroarylation reaction. The inversion barriers of the structures obtained are determined both theoretically and experimentally, and their chiroptical properties are reported. Preliminary studies on the post-synthetic functionalization of these thiahelicenes and their transformation into azahelicenes are also presented. In addition, a straightforward one-step protocol is developed, which wraps the initially obtained chryseno[3,4-b]naphtho[1,2-d]thiophenes into bowl-shaped pleiadene derivatives without erosion of the enantiopurity. The number of structurally related products that are obtained with high enantioselectivity enables the establishment of comprehensive correlations between the structure and conformational stability or (chir)optical properties." @default.
- W4319333012 created "2023-02-08" @default.
- W4319333012 creator A5021749466 @default.
- W4319333012 creator A5043055472 @default.
- W4319333012 creator A5048442714 @default.
- W4319333012 creator A5058517447 @default.
- W4319333012 creator A5065143464 @default.
- W4319333012 creator A5085758769 @default.
- W4319333012 creator A5085933802 @default.
- W4319333012 creator A5087635405 @default.
- W4319333012 date "2023-03-17" @default.
- W4319333012 modified "2023-10-17" @default.
- W4319333012 title "Enantioselective Au‐Catalyzed Synthesis of Thia[5]‐ and Thia[6]helicenes and Their Transformation into Bowl‐shaped Pleiadenes" @default.
- W4319333012 cites W1658488588 @default.
- W4319333012 cites W1968856580 @default.
- W4319333012 cites W1971015155 @default.
- W4319333012 cites W1973386467 @default.
- W4319333012 cites W1988091937 @default.
- W4319333012 cites W2007731282 @default.
- W4319333012 cites W2012331842 @default.
- W4319333012 cites W2020721890 @default.
- W4319333012 cites W2024189026 @default.
- W4319333012 cites W2042479758 @default.
- W4319333012 cites W2042915585 @default.
- W4319333012 cites W2047735309 @default.
- W4319333012 cites W2058848030 @default.
- W4319333012 cites W2074484279 @default.
- W4319333012 cites W2076595770 @default.
- W4319333012 cites W2085473316 @default.
- W4319333012 cites W2087926681 @default.
- W4319333012 cites W2089759965 @default.
- W4319333012 cites W2092609098 @default.
- W4319333012 cites W2095218708 @default.
- W4319333012 cites W2105327483 @default.
- W4319333012 cites W2119168357 @default.
- W4319333012 cites W2124490553 @default.
- W4319333012 cites W2127244468 @default.
- W4319333012 cites W2127364198 @default.
- W4319333012 cites W2127835896 @default.
- W4319333012 cites W2138443498 @default.
- W4319333012 cites W2143981217 @default.
- W4319333012 cites W2152602411 @default.
- W4319333012 cites W2175728713 @default.
- W4319333012 cites W2236937778 @default.
- W4319333012 cites W2320078993 @default.
- W4319333012 cites W2320934425 @default.
- W4319333012 cites W2333827620 @default.
- W4319333012 cites W2401822825 @default.
- W4319333012 cites W2474046955 @default.
- W4319333012 cites W2513728282 @default.
- W4319333012 cites W2554334762 @default.
- W4319333012 cites W2582149366 @default.
- W4319333012 cites W2587295205 @default.
- W4319333012 cites W2600730046 @default.
- W4319333012 cites W2729995910 @default.
- W4319333012 cites W2783319682 @default.
- W4319333012 cites W2789720320 @default.
- W4319333012 cites W2794399200 @default.
- W4319333012 cites W2806125820 @default.
- W4319333012 cites W2911312900 @default.
- W4319333012 cites W2961657701 @default.
- W4319333012 cites W2976975509 @default.
- W4319333012 cites W2977936184 @default.
- W4319333012 cites W2995696397 @default.
- W4319333012 cites W2997682160 @default.
- W4319333012 cites W3001451345 @default.
- W4319333012 cites W3012482155 @default.
- W4319333012 cites W3037417052 @default.
- W4319333012 cites W3083947556 @default.
- W4319333012 cites W3088849751 @default.
- W4319333012 cites W3114134882 @default.
- W4319333012 cites W3119374153 @default.
- W4319333012 cites W3128521247 @default.
- W4319333012 cites W3138876650 @default.
- W4319333012 cites W3163288367 @default.
- W4319333012 cites W3198336364 @default.
- W4319333012 cites W4200079388 @default.
- W4319333012 cites W4210332256 @default.
- W4319333012 cites W4288038221 @default.
- W4319333012 cites W4294670328 @default.
- W4319333012 cites W4306743363 @default.
- W4319333012 cites W4307983852 @default.
- W4319333012 cites W4309511905 @default.
- W4319333012 doi "https://doi.org/10.1002/adma.202211279" @default.
- W4319333012 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36747350" @default.
- W4319333012 hasPublicationYear "2023" @default.
- W4319333012 type Work @default.
- W4319333012 citedByCount "3" @default.
- W4319333012 countsByYear W43193330122023 @default.
- W4319333012 crossrefType "journal-article" @default.
- W4319333012 hasAuthorship W4319333012A5021749466 @default.
- W4319333012 hasAuthorship W4319333012A5043055472 @default.
- W4319333012 hasAuthorship W4319333012A5048442714 @default.
- W4319333012 hasAuthorship W4319333012A5058517447 @default.
- W4319333012 hasAuthorship W4319333012A5065143464 @default.
- W4319333012 hasAuthorship W4319333012A5085758769 @default.
- W4319333012 hasAuthorship W4319333012A5085933802 @default.
- W4319333012 hasAuthorship W4319333012A5087635405 @default.
- W4319333012 hasBestOaLocation W43193330121 @default.
- W4319333012 hasConcept C146686406 @default.