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- W4319460249 abstract "Abstract 2‑Boryl allylboronates, which contain both a C(sp2)–B bond and a C(sp3)–B bond, are attractive synthetic intermediates due to their diverse reactivity profiles toward a wide range of organic transformations. We report a facile approach to (Z)-2‑boryl allylboronates through a Pt/Zn-promoted diborylation reaction of readily available propargylic amines. An array of valuable (Z)-2‑boryl allylboronates were obtained in up to 73% yield in the presence of 2.5 mol% of Pt(PPh3)4 and 50 mol% of ZnBr2." @default.
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- W4319460249 date "2023-02-08" @default.
- W4319460249 modified "2023-09-26" @default.
- W4319460249 title "Synthesis of 2‑Boryl Allylboronates by a Bimetallic Platinum/Zinc-Promoted Diborylation of Propargylic Amines" @default.
- W4319460249 doi "https://doi.org/10.1055/a-2030-6797" @default.
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