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• W4319600770 abstract "In this work, the use of N-methyl-N-propylpiperidinium difluoro(oxalato)borate Pip13DFOB ionic liquid (IL), originally synthesized in our laboratory, as an additive for liquid electrolytes in lithium-ion batteries (LIBs), is proposed. The synthesized IL exhibits glass and melting transitions at −70.9 °C and 17.1 °C, respectively, and a thermal decomposition temperature over 230 °C. A mixture based on 1.0 M LiPF6 in 1:1 v/v ethylene carbonate (EC): dimethyl carbonate (DMC) electrolyte solution (so called LP30) and the IL was prepared and tested in lithium metal cells versus two different commercially available carbonaceous electrodes, i.e., graphite (KS6) and graphene (GnP), and versus a high voltage LiNi0.5Mn1.5O4 (LNMO) cathode. A noticeable improvement was observed for Li|LNMO cells with an IL-added electrolyte, which exhibited a high specific capacity above 120 mAh g−1 with a Coulombic efficiency above 93% throughout 200 cycles, while the efficiency fell below 80% after 80 cycles with the absence of IL. The results confirm that the IL is promising additive for the electrolyte, especially for a longer cycle life of high-voltage cells." @default.
• W4319600770 created "2023-02-09" @default.
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• W4319600770 date "2023-02-08" @default.
• W4319600770 modified "2023-09-30" @default.
• W4319600770 title "Effects of Difluoro(oxalato)borate-Based Ionic Liquid as Electrolyte Additive for Li-Ion Batteries" @default.
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• W4319600770 doi "https://doi.org/10.3390/ma16041411" @default.
• W4319600770 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36837039" @default.
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