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- W4319662754 abstract "A cadmium-based metal–organic framework (Cd-MOF) is synthesized in a facile manner at ambient temperature by an easy slow diffusion process. The three-dimensional (3D) structure of Cd-MOF is authenticated by single-crystal X-ray diffraction studies and exhibits a cuboid-shaped morphology with an average edge length of ∼1.13 μm. The prepared Cd-MOF was found to be electroactive in nature, which resulted in a specific capacitance of 647 F g–1 at 4 A g–1 by maintaining a retention of ∼78% over 10,000 successive cycles in the absence of any binder. Further, to distinguish the efficiency of Cd-MOF electrodes, different electrolytes (NaOH, KOH, and LiOH) were explored, wherein NaOH revealed a higher capacitive response due to its combined effect of ionic and hydrated ionic radii. To investigate the practical applicability, an asymmetric supercapacitor (ASC) device is fabricated by employing Cd-MOF as the positive electrode and activated carbon (AC) as the negative electrode, enabling it to light a commercial light-emitting diode (LED) bulb (∼1.8 V). The as-fabricated ASC device delivers comparable energy density and power density." @default.
- W4319662754 created "2023-02-10" @default.
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- W4319662754 date "2023-02-09" @default.
- W4319662754 modified "2023-10-14" @default.
- W4319662754 title "Effect of Electrolytic Cations on a 3D Cd-MOF for Supercapacitive Electrodes" @default.
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- W4319662754 doi "https://doi.org/10.1021/acs.inorgchem.2c03879" @default.
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