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- W4319726266 endingPage "2540" @default.
- W4319726266 startingPage "2531" @default.
- W4319726266 abstract "The treatment of 4,5-dimethyl-1,3-bis(2-pyridylmethyl)-1H-imidazolium chloride with M[N(SiMe3)2]2(THF)2 (M = Ca, Yb) in 1:2 molar ratio results in the formation of a carbene fragment, activation of the picolyl CH bond, and dearomatization of one of the pyridine rings and affords bis(amido) complexes [(NHC)MN(SiMe3)2]2 (M = Ca (2), Yb (3)) coordinated by a μ2-bridging pincer NHC amido ligand. Complexes 2 and 3 demonstrate high catalytic activity and excellent regio- and chemoselectivities in the intermolecular hydrophosphination of styrene with both primary and secondary phosphines. Complexes 2 and 3 enable selective addition of PhPH2, Ph2PH, (CH2)4NH, and (CH2)5NH to para-divinylbenzene with high conversions under mild conditions. Tandem hydrophosphination/hydroamination of para-divinylbenzene was also performed." @default.
- W4319726266 created "2023-02-11" @default.
- W4319726266 creator A5044989710 @default.
- W4319726266 creator A5049289774 @default.
- W4319726266 creator A5072554887 @default.
- W4319726266 date "2023-02-09" @default.
- W4319726266 modified "2023-10-15" @default.
- W4319726266 title "Heteroleptic Bis(amido) Ca(II) and Yb(II) NHC Pincer Complexes: Synthesis, Characterization, and Catalytic Activity in Intermolecular Hydrofunctionalization of C═C Bonds" @default.
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