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- W4319736420 abstract "Energy-transfer-mediated synthetic reactions play vital roles in the production of high-value-added organics, where the long-lived exciton harvesting is an essential precondition for the process. However, for semiconductors with strong excitonic effects like conjugated polymers, their predominant Frenkel exciton with a short lifetime in the unified framework gives rise to low efficiency photocatalysis. Herein, we propose the boosting of the charge-transfer exciton with a long-lived state by introducing spatially separated electron and hole regions. By taking polymeric carbon nitride (PCN) as a prototype, we demonstrate that sulfur doping leads to the formation of electron donor and acceptor motifs in the tri-s-triazine-based backbone, which would accommodate long-lived excitonic states with remarkable charge-transfer characteristics. The extraordinary long-lived charge-transfer exciton harvesting endows sulfur-doped PCN with high-efficiency photocatalytic performance in 1O2 generation and selective oxidation of organic sulfides. This work provides a brand new perspective for designing advanced photocatalysts for energy-transfer-mediated sunlight utilization." @default.
- W4319736420 created "2023-02-11" @default.
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- W4319736420 date "2023-02-09" @default.
- W4319736420 modified "2023-10-15" @default.
- W4319736420 title "Elemental Doping Boosts Charge-Transfer Excitonic States in Polymeric Photocatalysts for Selective Oxidation Reaction" @default.
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- W4319736420 doi "https://doi.org/10.1021/prechem.2c00001" @default.
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