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- W4319759417 endingPage "120672" @default.
- W4319759417 startingPage "120672" @default.
- W4319759417 abstract "A thermal/pH-sensitive interpenetrating network (IPN) hydrogel was prepared facilely from starch and poly(α-l-lysine) through amino-anhydride and azide-alkyne double-click reactions in one pot. The synthesized polymers and hydrogels were systematically characterized using different analytical techniques such as Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), scanning electron microscope (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and rheometer. The preparation conditions of the IPN hydrogel were optimized via one-factor experiments. Experimental results indicated the IPN hydrogel possessed pH and temperature sensitivity. Effect of different parameters (pH, contact time, adsorbent dosage, initial concentration, ionic strength, and temperature) on adsorption behavior were investigated in monocomponent system with cationic methylene blue (MB) and anionic Eosin Y (EY) as model pollutants. The results indicated that the adsorption process of the IPN hydrogel for MB and EY followed pseudo-second-order kinetics. The adsorption data for MB and EY fitted well with the Langmuir isotherm model, indicating monolayer chemisorption. The good adsorption performance was due to various active functional groups (-COOH, -OH, -NH2, etc.) in the IPN hydrogel. The strategy described here opens up a new way for preparing IPN hydrogel. The as-prepared hydrogel exhibits potential application and bright prospects as an adsorbent in wastewater treatment." @default.
- W4319759417 created "2023-02-11" @default.
- W4319759417 creator A5002351922 @default.
- W4319759417 creator A5030921116 @default.
- W4319759417 creator A5037776167 @default.
- W4319759417 creator A5051796390 @default.
- W4319759417 creator A5073190298 @default.
- W4319759417 creator A5043489482 @default.
- W4319759417 date "2023-06-01" @default.
- W4319759417 modified "2023-10-01" @default.
- W4319759417 title "Facile fabrication of a broad-spectrum starch/poly(α-l-lysine) hydrogel adsorbent with thermal/pH-sensitive IPN structure through simultaneous dual-click strategy" @default.
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- W4319759417 doi "https://doi.org/10.1016/j.carbpol.2023.120672" @default.
- W4319759417 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36906358" @default.