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• W4319790806 abstract "Abstract In this paper, we present the high‐pressure/high‐temperature synthesis and characterization of the potassium fluoridooxidoniobate K 3 Nb 2 O 4 F 5 . Single‐crystal analysis revealed that the phase crystallizes in the trigonal space group m ( hR 18) with a =5.799(2), c =21.371(4) Å, V =622.4(4) Å 3 and Z =3 at T =299 K exhibiting a structure type closely related to that of Ba 2 RbFe 2 F 9 . The assignment of the anion positions to oxygen and fluorine is based on crystallographic data and BLBS/CHARDI calculations. Further characterization via EDX spectroscopy was carried out, corroborating the ratio of K to Nb. Doping of the title compound with Mn 4+ was achieved in a secondary step using a ball‐mill, resulting in a red phosphor material, which was additionally analyzed by luminescence spectroscopy. The emission maximum is located at λ max =630 nm." @default.
• W4319790806 created "2023-02-11" @default.
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• W4319790806 date "2023-02-01" @default.
• W4319790806 modified "2023-09-26" @default.
• W4319790806 title "Crystal Structure, Characterization, and Luminescence Properties of Mn⁴⁺‐Doped K₃Nb₂O₄F₅" @default.
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• W4319790806 doi "https://doi.org/10.1002/ejic.202200714" @default.
• W4319790806 hasPublicationYear "2023" @default.
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