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• W4319791502 abstract "Abstract Multinary selenides A 4 B 10 Se 19 (A=Sn/Pb; B=Sb/Bi), including Sn 4 Bi 10 Se 19 , Pb 4 Sb 6.71 Bi 3.29 Se 19 , and Pb 4 Sb 3.43 Bi 6.57 Se 19 , were prepared by solid‐state reactions. These compounds adopt the Felbertalite structure type that crystallizes in the monoclinic space group C2/m (No. 12). Single‐crystal and powder X‐ray diffraction measurements studied the crystal structure and site preference of metal sites. They exhibit stacking of stepped layers (NaCl 111 ‐type) and ribbon‐shape (NaCl 100 ‐type) units that are connected via shared Se 2− ions. Electronic structure calculations indicated semiconducting properties and were verified by temperature‐dependent conductivity and Seebeck coefficient measurements. The thermoelectric properties show a maximum power factor of 1.06 μW ⋅ m −1 ⋅ K −2 at 550 K for Pb 4 Sb 6 Bi 4 Se 19 ." @default.
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• W4319791502 date "2023-02-01" @default.
• W4319791502 modified "2023-09-26" @default.
• W4319791502 title "Synthesis and Characterization of Multinary Selenides A ₄ B ₁₀ Se ₁₉ (A=Sn, Pb; B=Sb, Bi)" @default.
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• W4319791502 doi "https://doi.org/10.1002/zaac.202200271" @default.
• W4319791502 hasPublicationYear "2023" @default.
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