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• W4319791579 abstract "Abstract Low cost and high durability have made Portland cement the most widely‐used building material, but benefits are offset by environmental harm of cement production contributing 8–10% of total anthropogenic CO 2 gas emissions. High sulfur‐content materials (HSMs) are an alternative that can perform the binding roles as cements with a smaller carbon footprint, and possibly superior chemical, physical, and mechanical properties. Inverse vulcanization of 90 wt% sulfur with 10 wt% canola oil or sunflower oil to yield CanS or SunS, respectively. Notably, these HSMs prepared at temperatures ≤180 °C compared to >1200 °C hours for Portland cement CanS was combined with 5 wt% fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GGBFS), or metakaolin (MK) to give composites CanS‐FA, CanS‐SF, CanS‐GGBFS, and CanS‐MK, respectively. The analogous protocol with SunS likewise yielded SunS‐FA, SunS‐SF, SunS‐GGBFS, and SunS‐MK. Each of these HSMs exhibit high compressive mechanical strength, low water uptake values, and exceptional resistance to acid‐induced corrosion. All of the composites also exhibit superior compressive strength retention after exposure to acidic solutions, conditions under which Portland cement undergoes dissolution. The polymer cement‐pozzolan composites reported herein may thus serve as greener alternatives to traditional Portland cement in some applications." @default.
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• W4319791579 date "2023-02-04" @default.
• W4319791579 modified "2023-09-30" @default.
• W4319791579 title "Influence of pozzolans on plant <scp>oil‐sulfur</scp> polymer cements: More sustainable and <scp>chemically‐resistant</scp> alternatives to Portland cement" @default.
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• W4319791579 doi "https://doi.org/10.1002/app.53684" @default.
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