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• W4319826561 endingPage "6464" @default.
• W4319826561 startingPage "6454" @default.
• W4319826561 abstract "Herein, we report our study on the design and development of a novel photocarboxylation method. We have used an organic photoredox catalyst (PC, 4CzIPN) and differently substituted dihydropyridines (DHPs) in combination with an organic base (1,5,7-triazabicyclodec-5-ene, TBD) to access a proton-coupled electron transfer (PCET) based manifold. In depth mechanistic investigations merging experimental analysis (NMR, IR, cyclic voltammetry) and density-functional theory (DFT) calculations reveal the key activity of a H-bonding complex between the DHP and the base. The thermodynamic and kinetic benefits of the PCET mechanism allowed the implementation of a redox-neutral fixation process leading to synthetically relevant carboxylic acids (18 examples with isolated yields up to 75%) under very mild reaction conditions. Finally, diverse product manipulations were performed to demonstrate the synthetic versatility of the obtained products." @default.
• W4319826561 created "2023-02-11" @default.
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• W4319826561 date "2023-02-10" @default.
• W4319826561 modified "2023-10-14" @default.
• W4319826561 title "A Proton-Coupled Electron Transfer Strategy to the Redox-Neutral Photocatalytic CO₂ Fixation" @default.
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• W4319826561 doi "https://doi.org/10.1021/acs.joc.2c02952" @default.
• W4319826561 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36760023" @default.
• W4319826561 hasPublicationYear "2023" @default.
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