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• W4319836205 abstract "Although substantial advances have been made regarding synthetic chiral assemblies, obtaining the two-dimensional (2D) system with a sophisticated supramolecular chirality remains challenging. Herein, we report the switchable supramolecular chiral 2D materials via donor-acceptor interaction between a pyrene amphiphile and 7,7,8,8-tetracyanoquinodimethane (TCNQ). The resulting supramolecular chiral sheets spontaneously disassemble when TCNQ is irreversibly photo-reduced to its anion. Subsequent additions of TCNQ drive the disassembled molecules to repeatedly form optically active sheet structures, demonstrating that the assembled materials exist transiently only while TCNQ is supplied. The chiral sheets emit intense circularly polarized light with a large luminescence dissymmetric factor (glum)." @default.
• W4319836205 created "2023-02-11" @default.
• W4319836205 creator A5004305487 @default.
• W4319836205 creator A5004410171 @default.
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• W4319836205 date "2023-01-19" @default.
• W4319836205 modified "2023-10-13" @default.
• W4319836205 title "Assembly–disassembly switching of chiral sheet assembly for controlled circularly polarized luminescence" @default.
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• W4319836205 doi "https://doi.org/10.1002/pol.20220745" @default.
• W4319836205 hasPublicationYear "2023" @default.
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